Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Literature Information

Publication Date 2003-06-18
DOI 10.1039/B305430F
Impact Factor 6.222
Authors

Michael S. Hill, Peter B. Hitchcock


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Abstract

A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2PNC6H2-Me3-2,4,6)2] and MI2 (M = Ca, Sr, Ba) in THF.

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