Halogen-induced selectivity in heterogeneous epoxidation is an electronic effect—fluorine, chlorine, bromine and iodine in the Ag-catalysed selective oxidation of ethene

Literature Information

Publication Date 2003-04-16
DOI 10.1039/B302620E
Impact Factor 6.222
Authors

Richard M. Lambert, Rachael L. Cropley, Alifiya Husain, Mintcho S. Tikhov


View Original

Abstract

Selectivity promotion in the Ag-catalysed heterogeneous epoxidation of ethene correlates with halogen electron affinity showing that it is an electronic phenomenon rather than a steric or geometrical effect.

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