Exploration of the biomimetic synthesis of indole-diterpenemycotoxins: an unexpected cascade reaction during the attempted synthesis of emindole SB

Literature Information

Publication Date 2003-05-30
DOI 10.1039/B302105J
Impact Factor 6.222
Authors

J. Stephen Clark, James Myatt, Claire Wilson, Lee Roberts, Nigel Walshe


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Abstract

The key step in an attempted biomimetic synthesis of the indole-diterpene mycotoxin emindole SB delivers the pentacyclic compound resulting from 6-endo cyclisation instead of the product arising by the 5-exo reaction required in the putative biosynthetic pathway.

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