Cooperative effects in the complexation of anions and Lewis bases by a heteronuclear bifunctional Lewis acid
Literature Information
Publication Date
2003-02-14
DOI
10.1039/B212127A
Impact Factor
6.222
Authors
James D. Hoefelmeyer, François P. Gabbaï
View Original
Abstract
As shown by the complexation of electron-rich substrates to the heteronuclear bifunctional Lewis acid bis(μ-1,8-naphthalenediyl)(μ-chloride)methyltin-chlorogallium (1), the primary Lewis acidic site of this molecule is the triorganotin chloride moiety whose electron deficiency is enhanced through partial abstraction of its chloride ligand by the neighbouring gallium centre.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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