An oxime–carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water

Literature Information

Publication Date 2003-02-03
DOI 10.1039/B211742H
Impact Factor 6.222
Authors

Avelino Corma, Hermenegildo García, Antonio Leyva


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Abstract

A preformed oxime–carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active (>99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased activity.

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