The role of the hydrogen bond in dense nanoparticle–gas suspensions

Literature Information

Publication Date 2013-02-19
DOI 10.1039/C3CP43687J
Impact Factor 3.676
Authors

Maryam Tahmasebpoor, Lilian de Martín, Mojgan Talebi, Navid Mostoufi, J. Ruud van Ommen


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Abstract

The effect of surface characteristics on the interaction between nanoparticles and their agglomeration in dense gas suspensions is still not fully understood. It is known that when the surface is covered with hydroxyl groups, the interaction between nanoparticles becomes substantially stronger than in the absence of these groups; this strengthening is typically attributed to the formation of capillary bridges between the particles. However, this work shows that part of the increase of the interaction is due to the direct hydrogen bonds formed between the surfaces of the polar particles. Dry nitrogen was used to fluidize polar (hydrophilic) and apolar (hydrophobic) SiO2, TiO2 and Al2O3 particles, with a size ranging from 13 to 21 nm. The dry polar particles showed smaller bed expansion and larger minimum fluidization velocity compared to their apolar counterparts, indicating stronger interparticle forces. The results show the importance of including the formation of hydrogen bonds in the modeling of the interaction between dry and polar nanoparticles.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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