The anionic thia-Fries rearrangement of aryl triflates

Literature Information

Publication Date 2003-01-14
DOI 10.1039/B210648E
Impact Factor 6.222
Authors

Jonathan P. H. Charmant, Alan M. Dyke, Guy C. Lloyd-Jones


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Abstract

Aryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.

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