Novel supramolecular architectures in group 13 perfluoroaryl complexes. Synthesis and structures of [AlMe(C6F5)(μ-Me)]2 and GaMe(C6F5)2

Literature Information

Publication Date 2003-01-15
DOI 10.1039/B210024J
Impact Factor 6.222
Authors

Gregory S. Hair, Alan H. Cowley, John D. Gorden, Jamie N. Jones, Richard A. Jones, Charles L. B. Macdonald


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Abstract

Novel supramolecular architectures are observed in the solid state structures of [AlMe(C6F5)(μ-Me)]2 (1) and Ga(C6F5)2Me (2) via π–π stacking between C6F5 rings and intermolecular aryl-F→Ga interactions, respectively.

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Chemical Communications

Chemical Communications
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