New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage

Literature Information

Publication Date 2002-11-18
DOI 10.1039/B209445B
Impact Factor 6.222
Authors

Leigh F. Jones, Euan K. Brechin, David Collison, Andrew Harrison, Simon J. Teat, Wolfgang Wernsdorfer


View Original

Abstract

The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.

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