Vapour–liquid–liquid equilibria for the system 3-methoxypropionitrile + water in the vicinity of the upper critical end point

Literature Information

Publication Date 2002-08-28
DOI 10.1039/B203363A
Impact Factor 3.676
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Abstract

Vapour–liquid equilibria for the system 3-methoxypropionitrile + water were measured at several temperatures in the vicinity of the upper critical solution temperature. The static method was applied for the measurements. A new static apparatus for vapour–liquid equilibrium measurements up to 0.1 MPa has been designed and built. The test measurements performed for the system benzene + cyclohexane proved the high accuracy of the experimental procedure. The data of the vapour–liquid equilibria measurements for the system 3-methoxypropionitrile + water were modelled with the NRTL equation. The results of the calculations are discussed.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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