Second and third virial coefficients of three binary mixtures containing xenon, at 273 K: Comparison between Xe + C2H6, Xe + C2H4 and Xe + CO2

Literature Information

Publication Date 2002-08-29
DOI 10.1039/B203040C
Impact Factor 3.676
Authors

Catarina M. M. Duarte, Carlos Menduiña, Ana Aguiar-Ricardo, Manuel Nunes da Ponte


View Original

Abstract

This paper presents volumetric data for the mixtures xenon–ethane, xenon–ethene and xenon–carbon dioxide, with xenon mole fractions covering the whole composition range, at 273.00 K and pressures up to 3.5 MPa, measured using a Burnett apparatus. Second and third virial coefficients were derived for each mixture from the experimental compressibility factors, Z. Data for the pure components are also determined for consistency purposes and for the calculation of the unlike-interaction virial coefficients, B12, C112 and C122. Corrections for the effects of adsorption, and the procedure for computation of the compressibility factors and virial coefficients are described. In order to accomplish a better understanding of the intermolecular forces present in real fluids, the cross virial coefficients, B12, of the studied systems were theoretically calculated using a two centre Lennard–Jones (L–J) model, and compared with experimental data. The importance of the third virial cross coefficients C112 and C122 is discussed.

Related Literature

The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Fuquan Song, Roderick D. Cannon, Manfred Bochmann

2004-02-05 Communication

DOI: 10.1039/B314845A

Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

Christopher D. Ablan, Jason P. Hallett, Kevin N. West, Rebecca S. Jones, Charles A. Eckert, Charles L. Liotta, Philip G. Jessop

2003-11-03 Communication

DOI: 10.1039/B311146F

Nucleic acid binding properties of thyminyl and adeninyl pyrrolidine-amideoligonucleotide mimics (POM)

T. H. Samuel Tan, David T. Hickman, Jordi Morral, Ian G. Beadham, Jason Micklefield

2004-01-28 Communication

DOI: 10.1039/B315768G

Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation

Daniel J. Stasko, Kevin J. Perzynski, Mark A. Wasil

2004-02-16 Communication

DOI: 10.1039/B314475E

First total synthesis of murisolin

Naoyoshi Maezaki, Hiroaki Tominaga, Naoto Kojima, Minori Yanai, Daisuke Urabe, Tetsuaki Tanaka

2004-01-19 Communication

DOI: 10.1039/B312362F

Ns strategies: a highly versatile synthetic method for amines

Toshiyuki Kan, Tohru Fukuyama

2003-11-25 Feature Article

DOI: 10.1039/B311203A

Living cationic ring-opening polymerization by water-stable initiator: synthesis of a well-defined optically active polythiourethane

Atsushi Nagai, Bungo Ochiai, Takeshi Endo

2003-11-07 Communication

DOI: 10.1039/B310735C

New magnetically responsive polydicarbazole-magnetite nanoparticles

Jean-Paul Lellouche, Nurit Perlman, Augustine Joseph, Senthil Govindaraji, Ludmila Buzhansky, Aline Yakir, Ian Bruce

2004-02-06 Communication

DOI: 10.1039/B309375A

A novel azulene synthesis from the Ramirez ylide involving two different modes of its reaction with activated alkynes

Lee J. Higham, P. Gabriel Kelly, David M. Corr, Helge Müller-Bunz, Brian J. Walker, Declan G. Gilheany

2004-02-11 Communication

DOI: 10.1039/B316759C

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.