Second and third virial coefficients of three binary mixtures containing xenon, at 273 K: Comparison between Xe + C2H6, Xe + C2H4 and Xe + CO2
Literature Information
Catarina M. M. Duarte, Carlos Menduiña, Ana Aguiar-Ricardo, Manuel Nunes da Ponte
This paper presents volumetric data for the mixtures xenon–ethane, xenon–ethene and xenon–carbon dioxide, with xenon mole fractions covering the whole composition range, at 273.00 K and pressures up to 3.5 MPa, measured using a Burnett apparatus. Second and third virial coefficients were derived for each mixture from the experimental compressibility factors, Z. Data for the pure components are also determined for consistency purposes and for the calculation of the unlike-interaction virial coefficients, B12, C112 and C122. Corrections for the effects of adsorption, and the procedure for computation of the compressibility factors and virial coefficients are described. In order to accomplish a better understanding of the intermolecular forces present in real fluids, the cross virial coefficients, B12, of the studied systems were theoretically calculated using a two centre Lennard–Jones (L–J) model, and compared with experimental data. The importance of the third virial cross coefficients C112 and C122 is discussed.
Related Literature
The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states
Fuquan Song, Roderick D. Cannon, Manfred Bochmann
DOI: 10.1039/B314845A
Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch
Christopher D. Ablan, Jason P. Hallett, Kevin N. West, Rebecca S. Jones, Charles A. Eckert, Charles L. Liotta, Philip G. Jessop
DOI: 10.1039/B311146F
Nucleic acid binding properties of thyminyl and adeninyl pyrrolidine-amideoligonucleotide mimics (POM)
T. H. Samuel Tan, David T. Hickman, Jordi Morral, Ian G. Beadham, Jason Micklefield
DOI: 10.1039/B315768G
Exploration of the pentacyano-cyclo-pentadienide ion, C5(CN)5−, as a weakly coordinating anion and potential superacid conjugate base. Silylation and protonation
Christopher Richardson, Christopher A. Reed
DOI: 10.1039/B316122F
Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation
Daniel J. Stasko, Kevin J. Perzynski, Mark A. Wasil
DOI: 10.1039/B314475E
First total synthesis of murisolin
Naoyoshi Maezaki, Hiroaki Tominaga, Naoto Kojima, Minori Yanai, Daisuke Urabe, Tetsuaki Tanaka
DOI: 10.1039/B312362F
Ns strategies: a highly versatile synthetic method for amines
Toshiyuki Kan, Tohru Fukuyama
DOI: 10.1039/B311203A
Living cationic ring-opening polymerization by water-stable initiator: synthesis of a well-defined optically active polythiourethane
Atsushi Nagai, Bungo Ochiai, Takeshi Endo
DOI: 10.1039/B310735C
New magnetically responsive polydicarbazole-magnetite nanoparticles
Jean-Paul Lellouche, Nurit Perlman, Augustine Joseph, Senthil Govindaraji, Ludmila Buzhansky, Aline Yakir, Ian Bruce
DOI: 10.1039/B309375A
A novel azulene synthesis from the Ramirez ylide involving two different modes of its reaction with activated alkynes
Lee J. Higham, P. Gabriel Kelly, David M. Corr, Helge Müller-Bunz, Brian J. Walker, Declan G. Gilheany
DOI: 10.1039/B316759C
You might also like
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














