Molar volume of 6Li, 7Li and natural Li in the liquid state

Literature Information

Publication Date 2002-08-13
DOI 10.1039/B201956F
Impact Factor 3.676
Authors

Yuta Shimizu, Akitoshi Mizuno, Tadahiko Masaki


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Abstract

The densities of natural Li, concentrated 6Li and concentrated 7Li in the liquid state were each measured by the two-sphere-Archimedes method. The measured density of natural Li in the liquid state was in good agreement with previous data. From these data the molar volumes of natural Li, concentrated 6Li and concentrated 7Li in the liquid state were calculated. Among those three kinds of liquid Li, the molar volume changes in an almost common straight line with the variation of the temperature. This indicates that no isotope effect can be seen between the molar volume in the liquid state of 6Li and that of 7Li within the present experimental error. The simple model calculation of the molar volume of liquid Li was performed based on the hard sphere model immersed in the uniform electron gas. Calculated molar volumes agree with experimental ones.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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