Comment on “Revisiting π backbonding: the influence of d orbitals on metal–CO bonds and ligand red shifts” by D. Koch, Y. Chen, P. Golub and S. Manzhos, Phys. Chem. Chem. Phys., 2019, 21, 20814

Literature Information

Publication Date 2020-02-20
DOI 10.1039/C9CP05951B
Impact Factor 3.676
Authors


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Abstract

We challenge the statement of Koch et al. that the M → CO charge transfer and the decrease of the CO stretching frequency in metal carbonyl complexes do not depend on the metal d orbitals. The approach of the authors is severely flawed and leads to misleading conclusions.

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