Rate constants for the reactions of NO3•, SO4•− and Cl• radicals with formate and acetate esters in aqueous solution

Literature Information

Publication Date 2001-06-01
DOI 10.1039/B101932P
Impact Factor 3.676
Authors

George V. Buxton, Jiaqiang Wang, G. Arthur Salmon


View Original

Abstract

Rate constants for the reactions of NO3•, SO4•− and Cl• with the esters methyl formate, ethyl formate, methyl acetate and ethyl acetate in aqueous solution have been measured using pulse radiolysis and laser flash photolysis. The reactivities of NO3•, SO4•− and Cl• are compared with •OH and found to be roughly in the order Cl•≈•OHNO3•≈SO4•−. The rates of reaction of NO3• with the formate esters in the aqueous phase are about four orders of magnitude faster than their corresponding gas phase reactions. In contrast, the rate constants for reaction of Cl• with formate and acetate esters in the aqueous phase are about 100 times smaller than the gas phase values.

Related Literature

K-edge XANES investigation of octakis(DMSO)lanthanoid(iii) complexes in DMSO solution and solid iodides

Paola D'Angelo, Valentina Migliorati, Riccardo Spezia, Simone De Panfilis, Ingmar Persson, Andrea Zitolo

2013-04-17 Paper

DOI: 10.1039/C3CP50842K

The impact of spectator species on the interaction of H2O2 with platinum – implications for the oxygen reduction reaction pathways

Ioannis Katsounaros, Josef C. Meier, Udo Benedikt, P. Ulrich Biedermann, Angel Cuesta, Alexander A. Auer, Karl J. J. Mayrhofer

2013-03-01 Paper

DOI: 10.1039/C3CP50649E

Local electronic structure of aqueous zinc acetate: oxygen K-edge X-ray absorption and emission spectroscopy on micro-jets

Edlira Suljoti, Kai F. Hodeck, Kathrin M. Lange, Mikhail A. Soldatov

2013-04-17 Communication

DOI: 10.1039/C3CP50686J

Controlled electrochemical deposition and transformation of hetero-nanoarchitectured electrodes for energy storage

Jonathon Duay, Eleanor Gillette, Junkai Hu

2013-04-17 Perspective

DOI: 10.1039/C3CP50724F

Spectral assignments and NMR parameter–structure relationships in borates using high-resolution 11B NMR and density functional theory

Oliver L. G. Alderman, Dinu Iuga, Andrew P. Howes, Diane Holland, Ray Dupree

2013-04-05 Paper

DOI: 10.1039/C3CP50772F

Unraveling the atomic structure of Ge-rich sulfide glasses

Gabriel J. Cuello, Shinji Kohara, Chris J. Benmore, David L. Price, Eugene Bychkov

2013-04-08 Paper

DOI: 10.1039/C3CP50536G

Photoinduced electron transfer of platinum(ii) bipyridine diacetylides linked by triphenylamine- and naphthaleneimide-derivatives and their application to photoelectric conversion systems

Yuma Matsumoto, Mai Tsubamoto, Ryoji Sugimura, Masatoshi Kozaki, Kenshi Kimoto, Munetaka Iwamura, Koichi Nozaki, Naoki Senju, Chiasa Uragami, Yohei Muramatsu, Akinori Konno

2013-02-28 Paper

DOI: 10.1039/C3CP50182E

Structure of Nb2O5–NaPO3 glasses by X-ray and neutron diffraction

U. Hoppe, L. Delevoye, L. Montagne, M. v. Zimmermann, A. C. Hannon

2012-12-03 Paper

DOI: 10.1039/C2CP42772A

In situ X-ray pair distribution function analysis of geopolymer gel nanostructure formation kinetics

John L. Provis, Breaunnah Bloomer, Neil J. Henson, Katharine Page

2013-02-22 Paper

DOI: 10.1039/C3CP44342F

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.