Adsorption and photochemistry of CH3CN and CH3CONH2 on powdered TiO2
Literature Information
Chih-Chung Chuang, Wen-Chun Wu, Ming-Xi Lee, Jong-Liang Lin
The adsorption and photochemistry of acetonitrile and acetamide on TiO2 have been studied by Fourier-transform infrared spectroscopy (FTIR). Adsorbed CH3CN, CH3CONH2, η2(N,O)-CH3CONH are formed after CH3CN adsorption on TiO2. The last two species are due to surface hydroxy groups attacking the electron-deficient carbon in the cyano group of the adsorbed acetonitrile. UV exposure causes decomposition of CH3CN(a) to CH2CN(a) and decomposition of CH3CONH2(a) and η2(N,O)-CH3CONH(a) to CH3COO(a), HCOO(a), NCO(a) and CN-containing species on the surface.
Related Literature
Pseudo Jahn–Teller origin of cis–trans and other conformational changes. The role of double bonds
Pablo Garcia-Fernandez, Yang Liu, Isaac B. Bersuker, James E. Boggs
DOI: 10.1039/C0CP00900H
‘Shape effects’ in metal oxide supported nanoscale goldcatalysts
Matthew B. Boucher, Simone Goergen, Nan Yi, Maria Flytzani-Stephanopoulos
DOI: 10.1039/C0CP02009E
The active site structure of nitrided and oxynitrided graphite as a cathode catalyst in a fuel cell
Hiroyuki Tominaga, Wataru Ikeda, Masatoshi Nagai
DOI: 10.1039/C0CP02209H
Fullerene derivative acceptors for high performance polymer solar cells
Youjun He, Yongfang Li
DOI: 10.1039/C0CP01178A
Temperature dependence of the surfactant film bending elasticity in a bicontinuous sugar surfactant based microemulsion: a quasielastic scattering study
Stefan Wellert, Matthias Karg, Olaf Holderer, André Richardt, Thomas Hellweg
DOI: 10.1039/C0CP02044C
Controlled nanostructures for applications in catalysis
Ferdi Schüth
DOI: 10.1039/C1CP90005F
Ammonia IRMS-TPD measurements on Brønsted acidity of proton-formed SAPO-34
Katsuki Suzuki, Takuma Nishio, Naonobu Katada, German Sastre, Miki Niwa
DOI: 10.1039/C0CP00961J
Aggregation behavior of gemini surfactants and their interaction with macromolecules in aqueous solution
Yuchun Han, Yilin Wang
DOI: 10.1039/C0CP01196G
Ion conducting particle networks in liquids: modeling of network percolation and stability
Anna Jarosik, Uwe Traub, Joachim Maier, Armin Bunde
DOI: 10.1039/C0CP01870H
You might also like
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure (1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure](https://static.chemtradehub.com/structs/761/761423-87-4-dbeb.webp)


