Reductive cleavage of the C–O bond of acetals and orthoesters: reduction by silane in the presence of a Rh–PPh3 complex

Literature Information

Publication Date 2003-04-17
DOI 10.1039/B302124F
Impact Factor 6.222
Authors

Tetsuo Ohta, Tsugumi Michibata, Kazuyuki Yamada, Ryohei Omori, Isao Furukawa


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Abstract

Reductions of acetals to ethers and of orthoester to acetal by hydrosilane using rhodium catalyst are described.

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