Phase equilibria of a lattice model of associating binary mixtures

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Publication Date
DOI 10.1039/A903737C
Impact Factor 3.676
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Abstract

We study a lattice model of an associating A–B binary mixture, which differs from the one originally proposed by Lin and Taylor (Phys. Rev. E, 1994, 49, 2058 and Phys. Rev. Lett., 1994, 73, 2863) because it allows interactions between all pairs of particles. This model can be mapped onto an Ising model with renormalized coupling parameters. The global phase diagram of the mixture is obtained as a function of the physical parameters. The appearance of closed loops of immiscibility is analysed in terms of the coupling parameters.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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