Structural trends in the sodalite family

Literature Information

Publication Date
DOI 10.1039/A903373D
Impact Factor 3.676
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Abstract

Correlations derived from the structural parameters of a wide range of gallium and germanium containing sodalites have been examined. This has allowed the effect of introducing gallium and germanium onto the framework sites to be studied. The framework expansion associated with gallium and germanium incorporation is principally accommodated by co-operative rotations about the axis and an increase in framework T–O–T bond angle. Correlations involving structural parameters such as framework T–O–T bond angle, T–O bond lengths and tetrahedral tilt angle have been examined and have been shown to be analogous to those found for their aluminosilicate counterparts.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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