Cationic benzyl zirconium heteroscorpionates: synthesis and characterization of a novel ethylene polymerisation catalyst showing an unusual temperature dependent polymerisation mechanism
Literature Information
Stefano Milione, Cosimo Montefusco, Tomas Cuenca, Alfonso Grassi
The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst [(bpzmp)Zr(CH2Ph)2]+[PhCH2B(C6F5)3]− which showed a temperature dependent polymerisation mechanism identified by variable temperature 1H NMR analysis of the catalyst solution.
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