(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate | CAS No. 929097-92-7

(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Basic Information

CAS Number

929097-92-7

Molecular Formula

C56H41O4ψ2

Molecular Weight

865.07 g/mol

AD

Basic Physical Properties

Melting Point

188-193 °C

Specific Rotation

+210° (c=1.0, CHCl3)

C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC5=CC=CC=C5C6=C4OP(=O)(OC7=C6C8=CC=CC=C8C=C7[Si](C9=CC=CC=C9)(C1=CC=CC=C1)C1=CC=CC=C1)O

InChI

InChI=1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)

InChIKey

BDQOCXQVIFQJRK-UHFFFAOYSA-N

Complexity

1320

Safety Information

View Safety Information

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation
H319 Causes serious eye irritation
Serious eye damage/eye irritation
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

  • (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • 2,6-Bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosph epin-4-ol 4-oxide
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(triphenylsilyl)-, 4-oxide, (11bS)-
  • (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (S)-2,2′-Dihydroxy-3,3′-bis(triphenylsilyl)-1,1′-binaphthalene cyclic phosphate
  • (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
  • (S)-3,3 inverted exclamation mark -Bis(triphenylsilyl)-1,1 inverted exclamation mark -binaphthyl-2,2 inverted exclamation mark -diyl Hydrogenphosphate
  • (R)-3,3 inverted exclamation mark -Bis(triphenylsilyl)-1,1 inverted exclamation mark -binaphthyl-2,2 inverted exclamation mark -diyl Hydrogenphosphate
  • (13-hydroxy-13-oxo-16-triphenylsilyl-12,14-dioxa-13$l^{5-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-10-yl)-triphenylsilane
  • R-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (13-hydroxy-13-oxo-16-triphenylsilyl-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-10-yl)-triphenylsilane
  • SCHEMBL296667
  • (R)-()-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
  • (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • 791616-55-2
  • (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate
  • (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, min. 98% [(R)-TiPSY]
  • SY078377
  • D77214
  • J-524233
  • (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate
  • (R)-( C)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • AS-72739
  • 13-HYDROXY-10,16-BIS(TRIPHENYLSILYL)-12,14-DIOXA-13??-PHOSPHAPENTACYCLO[13.8.0.0(2),(1)(1).0(3),?.0(1)?,(2)(3)]TRICOSA-1(15),2(11),3,5,7,9,16,18,20,22-DECAEN-13-ONE
  • CS-B0723
  • AKOS015969423
  • BCP12729

MDL Number

MFCD09265079

FAQ

What are the physical and chemical properties of (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (CAS: 929097-92-7)?

The compound (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate has a crystalline form with a molecular weight of approximately 1157.38 g/mol. It has low solubility in water and organic solvents. The compound shows moderate reactivity with nucleophiles and is stable under normal conditions.

How is (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (CAS: 929097-92-7) typically synthesized?

This compound is typically synthesized via a multi-step process involving the formation of the 1,1'-binaphthyl skeleton followed by silylation and hydrogen phosphate derivatization. The synthesis requires careful control of the reaction conditions to achieve high purity and yield.

What industries use (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (CAS: 929097-92-7)?

This compound is primarily used in the pharmaceutical industry for its chiral structure, which can be used in the synthesis of pharmaceuticals. It is also utilized in the polymer and semiconductor industries for its unique electronic properties and structure.

What precautions should be taken when handling (R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (CAS: 929097-92-7)?

When handling this compound, appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat should be worn. It should be stored in a fume hood and handled in a well-ventilated area. Spills should be cleaned up promptly using appropriate absorbents, and the material safety data sheet (MSDS) should be consulted for detailed safety information.

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