3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) | CAS No. 900169-53-1

3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1)

Basic Information

CAS Number

900169-53-1

Molecular Formula

C38H40Br2Cl2N4Ru

Molecular Weight

885.56 g/mol

AD

Basic Physical Properties

Melting Point

140°C (dec.)

BrC1=CC=CN=C1.CC2=C(C(C)=CC(C)=C2)N(C3[Ru](Cl)(Cl)=CC4=CC=CC=C4)CCN3C5=C(C=C(C=C5C)C)C.BrC6=CC=CN=C6

InChI

InChI=1S/C21H26N2.C7H6.2C5H4BrN.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7-5-3-2-4-6-7;2*6-5-2-1-3-7-4-5;;;/h9-12H,7-8H2,1-6H3;1-6H;2*1-4H;2*1H;/q;;;;;;+2/p-2

InChIKey

YDOACSUCKSODBO-UHFFFAOYSA-L

LogP

11.14751999999999

Topological Polar Surface Area

32.260000000000005 Ų

Hydrogen Bond Donor/Acceptor

0 / 4

Safety Information

View Safety Information

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral
H315 Causes skin irritation
Skin corrosion/irritation
H319 Causes serious eye irritation
Serious eye damage/eye irritation
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

  • Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II)
  • [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]bis(2-bromopyridine)dichloro(phenylmethylene)ruthenium
  • Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]-(benzylidene)bis(3-bromopyridine)r
  • Grubbs Catalyst, 3nd Generation
  • BENZYLIDENE-[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIDIN-2-YLIDENE]-DICHLORORUTHENIUM
  • 3-BROMOPYRIDINE
  • benzylidene-[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichlororuthenium
  • 3rd Generation
  • Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium
  • Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]-(benzylidene)bis(3-bromopyridine)ruthenium(II)

MDL Number

MFCD09265164

FAQ

What is 3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) (CAS: 900169-53-1)?

3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) is a complex organic compound with CAS number 900169-53-1. It consists of a bromopyridine core linked to a ruthenium complex through benzylidene and dichloro bridges. This compound exhibits unique chemical properties suitable for various applications in organic synthesis and catalysis.

What are the main uses of 3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) (CAS: 900169-53-1)?

The main uses of 3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) include catalytic applications in organic synthesis, particularly in cross-coupling reactions. It is also used in the preparation of various functionalized compounds and as a Lewis acid in certain chemical transformations.

Is 3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) (CAS: 900169-53-1) safe?

3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) is generally safe for use when handled with appropriate precautions. It is important to follow standard safety guidelines, including proper ventilation, use of personal protective equipment (PPE), and handling in a fume hood. Spills should be cleaned up promptly and according to laboratory safety protocols.

How should 3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) (CAS: 900169-53-1) be stored?

3-Bromopyridine - benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium (2:1) should be stored in a cool, dry place, away from direct sunlight and sources of heat. It should be kept in a tightly sealed container to prevent degradation and contamination. Stable storage conditions include a temperature range of 15-25°C and relative humidity below 60%. Proper labeling and documentation are essential for safe management of this compound.

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