Bismuth(III) trifluoromethanesulfonate

Basic Information

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CAS Number

88189-03-1

Molecular Formula

C3BiF9O9S3

Molecular Weight

656.19 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Carboxylic Acids

Fine Chemicals Specialty Chemicals UV Stabilizers

Water Treatment Chemicals Coagulants and Flocculants Inorganic Coagulants

Water Treatment Chemicals Disinfectants Chlorine Compounds

Basic Physical Properties

Melting Point

>300 °C

Solubility

Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.

SMILES

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C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]

InChI

InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChIKey

NYENCOMLZDQKNH-UHFFFAOYSA-K

LogP

3.39660

Complexity

145

Safety Information

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GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Hazard Class

Class 8 Class 8

Stability

hygroscopic

Sensitiveness

Hygroscopic

Synonyms & References

English

Bismuth(III) trifluoromethanesulfonate
BISMUTH TRIFLUOROMETHANESULFONATE, hydrate
Bismuth(III) Trifluoromethanesulfonate (3:1)
bismuth,trifluoromethanesulfonate
Bi(OTf)3
Bismuth tris(trifluoromethanesulfonate)
Bismuth(III) triflate
51KD8E1741
Bismuth(3+) triflate
Bismuth(III) trifluoromethanesulfonate, 98%
Bismuth triflate [MI]
Bismuth(3+) trifluoromethanesulfonate
bismuth (III) triflate
KSC491A7J
NYENCOMLZDQKNH-UHFFFAOYSA-K
Bismuth(III)trifluoromethanesulfonate
Methanesulfonic acid, 1,1,1-trifluoro-, bismuth(3+) salt (3:1)
TRA0161519
Bism
Methanesulfonic acid, trifluoro-, bismuth(3+) salt (9CI)
Bismuth triflate
Trifluoromethanesulfonic acid bismuth(3+) salt
AKOS015853174
UNII-51KD8E1741
bismuth;trifluoromethanesulfonate
Bismuth (III) trifluoromethanesulfonate
bismuth(3+) ion tritrifluoromethanesulfonate
bismuth(3+) tritriflate
GS-6911
Bismuth(III) trifluoromethanesulphonate
MFCD02093669

MDL Number

MFCD08272314

Customs Code

2904909090

FAQ

What is Bismuth(III) trifluoromethanesulfonate (CAS: 88189-03-1)?

Bismuth(III) trifluoromethanesulfonate is an inorganic compound with the formula Bi(OTf)3, where Tf represents trifluoromethanesulfonate. It is a colorless to white crystalline solid with a melting point of about 150°C. This compound is known for its stability and has been used in various applications due to its unique properties.

What are the main uses of Bismuth(III) trifluoromethanesulfonate (CAS: 88189-03-1)?

Bismuth(III) trifluoromethanesulfonate is primarily used as a catalyst in organic synthesis, particularly in Friedel-Crafts alkylation and acylation reactions. It is also used in the preparation of certain pharmaceuticals and as a reagent in analytical chemistry. Due to its Lewis acidic nature, it can serve as a base in some reactions.

Is Bismuth(III) trifluoromethanesulfonate (CAS: 88189-03-1) safe?

Bismuth(III) trifluoromethanesulfonate is generally considered safe for laboratory use when handled properly. However, it should be stored in a cool, dry place away from direct sunlight. It is non-toxic but may cause skin irritation. Protective gloves and goggles should be worn during handling to prevent skin and eye contact. Inhalation of dust should be avoided.

How should Bismuth(III) trifluoromethanesulfonate (CAS: 88189-03-1) be stored?

Bismuth(III) trifluoromethanesulfonate should be stored in a sealed container in a cool, dry place away from direct sunlight and heat sources. It should be kept at room temperature (15-25°C) and in a low humidity environment to maintain its stability. Avoid contact with moisture and other reactive materials. It is advisable to store it in a fume hood or a well-ventilated area to prevent inhalation of dust or fumes.