3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate | CAS No. 870077-94-4

3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate

Basic Information

CAS Number

870077-94-4

Molecular Formula

C25H38F6IrNP2-

Molecular Weight

720.7 g/mol

AD

Basic Physical Properties

CC(C)P(C1=C(CC2=CC=CC=C21)N(C)C)C(C)C.C1CC=CCCC=C1.F[P-](F)(F)(F)(F)F.[Ir]

InChI

InChI=1S/C17H26NP.C8H12.F6P.Ir/c1-12(2)19(13(3)4)17-15-10-8-7-9-14(15)11-16(17)18(5)6;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h7-10,12-13H,11H2,1-6H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;

InChIKey

MMDIEIPTBOTQOH-ONEVTFJLSA-N

LogP

10.82680

Complexity

471

Synonyms & References

English

  • 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate
  • 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I)hexafluorophosphate
  • (1Z,5Z)-cycloocta-1,5-diene;3-di(propan-2-yl)phosphanyl-N,N-dimethyl-1H-inden-2-amine;iridium;hexafluorophosphate
  • DTXSID90855869
  • 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate, min. 98%
  • 870077-94-4
  • A917463
  • (1Z,5Z)-cycloocta-1,5-diene,3-di(propan-2-yl)phosphanyl-N,N-dimethyl-1H-inden-2-amine,iridium,hexafluorophosphate

MDL Number

MFCD09264283

FAQ

What are the physical and chemical properties of 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate (CAS: 870077-94-4)?

The compound is a solid with a crystalline form. Its molecular weight is approximately 721.8 g/mol. It is poorly soluble in water but soluble in many organic solvents like dichloromethane. The compound exhibits low reactivity under normal conditions but can be sensitive to moisture and air. It is typically used in catalytic applications.

How is 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate (CAS: 870077-94-4) typically synthesized?

The compound is synthesized through a reaction involving iridium(I) hexafluorophosphate and a phosphine ligand in the presence of a base. The reaction involves the formation of a complex where the phosphine ligand binds to the iridium center, and the resulting compound is isolated in a crystalline form. The synthesis typically requires controlled conditions to ensure high yield and selectivity.

What industries use 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate (CAS: 870077-94-4)?

This compound is primarily used in the field of catalysis, particularly in polymerization reactions. It finds applications in the production of high-performance polymers and in the synthesis of pharmaceuticals. Its use in semiconductors and sensors is also becoming more prevalent due to its unique catalytic properties.

What precautions should be taken when handling 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)iridium(I) hexafluorophosphate (CAS: 870077-94-4)?

Proper personal protective equipment (PPE) including gloves, safety goggles, and lab coat should be worn when handling this compound. It should be stored in a dry and well-ventilated area, away from moisture and heat. Spills should be handled with care, using appropriate absorbents, and the area should be thoroughly cleaned. Always consult the Material Safety Data Sheet (MSDS) for specific handling and disposal instructions.

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