1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)

Basic Information

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CAS Number

851308-40-2

Molecular Formula

C48H44FeP2

Molecular Weight

738.67 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Basic Physical Properties

Melting Point

No data available

Boiling Point

No data available

Density

No data available

Flash Point

No data available

Vapor Pressure

No data available

Specific Rotation

-163° ±10° (c 0.5, CHCl3)

SMILES

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Cc1cc(cc(c1)P(c2cc(cc(c2)C)C)[C@H](C)[C]3[CH][CH][CH][C]3P(c4cccc5c4cccc5)c6cccc7c6cccc7)C.[CH]1[CH][CH][CH][CH]1.[Fe]

InChI

InChI=1S/C43H44P2.C5H10.Fe/c1-29-23-30(2)26-36(25-29)44(37-27-31(3)24-32(4)28-37)33(5)38-19-12-22-41(38)45(42-20-10-15-34-13-6-8-17-39(34)42)43-21-11-16-35-14-7-9-18-40(35)43;1-2-4-5-3-1;/h6-11,13-18,20-21,23-28,33,38,41H,12,19,22H2,1-5H3;1-5H2;/t33-,38?,41?;;/m1../s1

InChIKey

IWQSRCJVJZWHFY-HYUNQDLJSA-N

LogP

10.93267999999999

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

862

Safety Information

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Hazard Statement

Synonyms & References

English

r-np-xyl
1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1S)-1-[bis(3,5-dim ethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3 ,4,5-cyclopentanepentayl, iron salt (1:1:1)
(r,r)-1-{1-[bis(3,5-dimethylphenyl)phosphino]ethyl}-2-[di(1-naphthyl)phosphino]ferrocene (acc to cas)
(2R)-1-[(1R)-1-[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]ETHYL]-2-(DI-1-NAPHTHALENYLPHOSPHINO)FERROCENE
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino) ferrocenyl]ethyldi-3,5-xylylphosphine, min. 97%
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]eth
(R)-(-)-1-[(S)-2-(Di-1-naphthylphosphino)ferrocenyl]ethyldi-3,5-xylylphosphine,Min.97%
(R)-1-{(SP)-2-[Di(1-naphthyl)phosphino]ferrocenyl}ethyldi(3,5-xylyl)phosphine
(R)-1-{(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE
(R)-1-((Sp)-2-[Di(1-naphthyl)phosphino]ferrocenyl)ethyldi(3,5-xylyl)phosphine
Josiphos SL-J404-1

MDL Number

MFCD08561162

Customs Code

29319090

FAQ

What are the physical and chemical properties of 1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) (CAS: 851308-40-2)?

This compound is a complex organic iron salt with a crystalline form. It has a high molecular weight due to the presence of multiple cyclopentane rings and phosphine ligands. The compound is soluble in organic solvents like THF and dimethylformamide. It exhibits significant reactivity in coordination chemistry, particularly in catalytic applications. Its solubility and reactivity make it valuable in various chemical transformations.

How is 1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) (CAS: 851308-40-2) typically synthesized?

This compound is synthesized through a multi-step process involving the complexation of iron with the specified cyclopentane-derived ligands. The synthesis typically requires the use of ligands and iron precursor in organic solvents. The yield and selectivity are influenced by the reaction conditions and choice of ligands. The method involves careful control of pH and temperature to achieve the desired product.

What industries use 1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) (CAS: 851308-40-2)?

This compound is used primarily in the chemical industry, particularly in catalysis, for the synthesis of various organic compounds. It is also of interest in material science for its potential applications in sensors and semiconductors. The compound's reactivity makes it suitable for use in the pharmaceutical industry for the production of certain drugs.

What precautions should be taken when handling 1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1R)-1-[bis(3,5-dimethylphenyl)phosphino]ethyl]-2-(di-1-naphthalenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) (CAS: 851308-40-2)?

When handling this compound, it is essential to wear appropriate personal protective equipment (PPE) including gloves, goggles, and a lab coat. Store it in a dry, well-ventilated area away from direct sunlight. Use a fume hood during handling to minimize exposure. In case of spill, neutralize with an appropriate chemical and clean up according to the material safety data sheet (SDS). Always refer to the SDS for detailed safety information.