[chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans | CAS No. 54806-25-6

[chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans

Basic Information

CAS Number

54806-25-6

Molecular Formula

C46H37ClNiP2

Molecular Weight

747.91 g/mol

AD

Basic Physical Properties

Melting Point

187-191°C

Cl[Ni](c1cccc2ccccc12)(P(c3ccccc3)(c4ccccc4)c5ccccc5)P(c6ccccc6)(c7ccccc7)c8ccccc8

InChI

InChI=1S/2C18H15P.C10H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-10-8-4-3-7-9(10)5-1;;/h2*1-15H;1-7H;1H;/q;;;;-1/p+1

InChIKey

QSKIVJZTVZFYFP-UHFFFAOYSA-O

LogP

9.055600000000007

Topological Polar Surface Area

0.0 Ų

Hydrogen Bond Donor/Acceptor

0 / 0

Safety Information

View Safety Information

Hazard Statement

H317 May cause an allergic skin reaction
Sensitization, Skin
H350 May cause cancer
Carcinogenicity

Hazard Class

Class IRRITANT Class IRRITANT

Synonyms & References

English

  • TRANS-CHLORO(1-NAPHTHYL)BIS(TRIPHENYLPHOSPHINE)-NICKEL
  • Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II)
  • trans-Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II)
  • Naphthalen-1-ylbis(triphenylphosphoranyl)nickel(IV) chloride
  • oro(1-naphthyL
  • chloro-(1-naphthyl)-bis(triphenylphosphoranyl)nickel
  • Nickel, chloro-1-naphthalenylbis(triphenylphosphine)-, (SP-4-3)- (9CI, ACI)
  • trans-Naphthalen-1-ylbis(triphenylphosphoranyl)nickel(IV) Chloride
  • chloronickel,1H-naphthalen-1-ide,triphenylphosphanium
  • Nickel,chloro-1-naphthalenylbis(triphenylphosphine)-, (SP-4-3)-
  • trans-Chloro(1-naphthyl)bis-(triphenylphosphine)nickel
  • trans-Chloro(1-naphthyl)bis(triphenylphosphine)-nickel
  • [NiCl(1-naph)(PPh3)2]
  • [NiCl(1-naphthyl)(triphenylphosphine)2]
  • chloro(1-naphthalenyl)bis(triphenylphosphine)nickel
  • Ni(PPh3)2(1-naph)Cl
  • Ni(PPh3)2(1-naphthyl)Cl
  • chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickeliotriphenyl-lambda5-phosphane, trans

MDL Number

MFCD06800434

FAQ

What are the physical and chemical properties of [chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans (CAS: 54806-25-6)?

The compound [chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans, has a crystalline form and a molecular weight of approximately 1000 g/mol. It is slightly soluble in organic solvents and exhibits moderate reactivity in the presence of electrophiles. The compound is stable under standard laboratory conditions but requires a fume hood for handling to avoid inhalation of its vapors.

How is [chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans (CAS: 54806-25-6) typically synthesized?

This compound is synthesized through a complex multistep process involving nickel catalysis, phosphine ligands, and aromatic substitution reactions. The synthesis requires the use of specific catalysts and ligands, with high selectivity and yield. The exact reaction conditions and reagents are proprietary and detailed in the literature.

What industries use [chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans (CAS: 54806-25-6)?

This compound is primarily used in the pharmaceutical and semiconductor industries for its unique electronic properties. It plays a role in the development of new materials for electronic devices and is also used in the synthesis of complex organic compounds. Its applications in sensor technologies and polymer science are also being explored.

What precautions should be taken when handling [chloro(naphthalen-1-yl)(triphenyl-lambda5-phosphanyl)nickelio]triphenyl-lambda5-phosphane, trans (CAS: 54806-25-6)?

When handling this compound, it is essential to wear appropriate personal protective equipment (PPE) such as gloves and safety glasses. The compound should be used in a well-ventilated area or a fume hood to prevent inhalation of vapors. Spills should be promptly cleaned up with appropriate absorbent materials. Always consult the Material Safety Data Sheet (MSDS) for specific handling and disposal guidelines.

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