Lithium tetramethylpiperidide

Basic Information

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CAS Number

38227-87-1

Molecular Formula

C9H18LiN

Molecular Weight

147.2 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Heterocyclic Compounds

Pharmaceutical Chemicals Pharmaceutical Intermediates Heterocyclic Intermediates

Basic Physical Properties

SMILES

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[Li+].CC1(CCCC([N-]1)(C)C)C

InChI

InChI=1S/C9H18N.Li/c1-8(2)6-5-7-9(3,4)10-8;/h5-7H2,1-4H3;/q-1;+1

InChIKey

ANYSGBYRTLOUPO-UHFFFAOYSA-N

Complexity

116

Safety Information

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Hazard Statement

H261 In contact with water releases flammable gas
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases

H314 Causes severe skin burns and eye damage
Skin corrosion/irritation

Synonyms & References

English

Q1110352
N-lithio 2
2,2,6,6-tetramethylpiperidinyllithium
lithium 2,2,6,6-tetramethylpiperidin-1-ide
lithium tetramethylpiperidide
lithium 2,2,6,6-tetramethyl piperidin-1-ide
FT-0693463
DTXSID00453330
SCHEMBL379209
2,2,6,6 tetramethyl-lithio-piperidine
lithium;2,2,6,6-tetramethylpiperidin-1-ide
Lithium 2,2,6,6-tetramethylpiperidide, 97%
AS-76847
AKOS006280823
38227-87-1
Lithium 2,2,6,6-tetramethylpiperidide
A904616
LTMP
LiTMP
Piperidine, 2,2,6,6-tetramethyl-, lithium salt
lithium(1+) 2,2,6,6-tetramethylpiperidin-1-ide
ANYSGBYRTLOUPO-UHFFFAOYSA-N
lithium 2,2,6,6-tetramethyl piperidide
Piperidine,2,2,6,6-tetramethyl-, lithium salt (1:1)
LITHIUM TETRAMETHYLPIPERIDIDE
2,2,6,6-Tetramethylpiperidine lithium salt (1:1)
2,2,6,6-tetramethylpiperidinyl-lithium
58100-EP2280000A1
58100-EP2305682A1
58100-EP2308879A1
Li[(2,2,6,6-tetramethylpiperidino)]

MDL Number

MFCD00015910

FAQ

What is Lithium tetramethylpiperidide (CAS: 38227-87-1)?

Lithium tetramethylpiperidide (CAS: 38227-87-1) is a complex compound containing lithium and a tetramethylpiperidine ligand. It is typically represented by the formula [Li(C5H11)2N]2. This compound is known for its stability and reactivity in organic synthesis.

What are the main uses of Lithium tetramethylpiperidide (CAS: 38227-87-1)?

Lithium tetramethylpiperidide (CAS: 38227-87-1) is primarily used in organic synthesis as a powerful nucleophile. It can also serve as a protecting group in certain reactions and as an additive in some formulations.

Is Lithium tetramethylpiperidide (CAS: 38227-87-1) safe?

Lithium tetramethylpiperidide (CAS: 38227-87-1) is generally safe when handled with appropriate precautions. However, it should be stored away from heat and moisture, and proper protective equipment should be worn during use to avoid skin contact and inhalation.

How should Lithium tetramethylpiperidide (CAS: 38227-87-1) be stored?

Lithium tetramethylpiperidide (CAS: 38227-87-1) should be stored in a cool, dry environment, away from heat sources and moisture. It should be kept in a tightly sealed, airtight container to prevent moisture absorption and degradation.