(R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate | CAS No. 361342-51-0

(R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate

Basic Information

CAS Number

361342-51-0

Molecular Formula

C48H31O4P

Molecular Weight

702.73 g/mol

AD

Basic Physical Properties

Melting Point

288-292 °C (D)

OP1(=O)Oc2c(cc3c(c2c2c(O1)c(cc1c2C=CCC1)c1c2ccccc2cc2c1cccc2)cccc3)c1c2ccccc2cc2c1cccc2

InChI

InChI=1S/C48H31O4P/c49-53(50)51-47-41(43-35-19-7-1-13-29(35)25-30-14-2-8-20-36(30)43)27-33-17-5-11-23-39(33)45(47)46-40-24-12-6-18-34(40)28-42(48(46)52-53)44-37-21-9-3-15-31(37)26-32-16-4-10-22-38(32)44/h1-5,7-17,19-28H,6,18H2,(H,49,50)

InChIKey

SZKDXDJLUYHXLW-UHFFFAOYSA-N

LogP

13.284599999999978

Topological Polar Surface Area

55.760000000000005 Ų

Hydrogen Bond Donor/Acceptor

1 / 4

Safety Information

View Safety Information

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation
H319 Causes serious eye irritation
Serious eye damage/eye irritation
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

  • (R)-3,3′-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (11Br)-2,6-Di-9-Anthracenyl-4-Hydroxy-Dinaphtho[2,1-D:1Μ,2Μ-F][1,3,2]Dioxaphosphepin-4-Oxide
  • (11Br)-2,6-Di(anthracen-9-yl)-4-hydroxydinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
  • (R)-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
  • S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
  • (11bR)-2,6-Di-9-anthracenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

MDL Number

MFCD11045406

FAQ

What are the physical and chemical properties of (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate (CAS: 361342-51-0)?

The compound (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate is a crystalline solid with a high molecular weight. It is poorly soluble in water but soluble in organic solvents like dichloromethane. The compound is known for its photostability and high electronic conductivity, making it reactive in organic synthesis. It is also known for its strong electronic interactions and excellent solubility in nonpolar solvents.

How is (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate (CAS: 361342-51-0) typically synthesized?

(R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate is typically synthesized through the condensation of anthracene-9-boronic acid and 1,1'-binaphthyl-2,2'-dionaldehyde under controlled conditions. The reaction is catalyzed by palladium(II) acetate and tri-o-tolylphosphine. The yield is usually around 70-80%, and the product is purified by recrystallization from an appropriate solvent.

What industries use (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate (CAS: 361342-51-0)?

The compound (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate is widely used in the pharmaceutical industry for the development of photostable drugs. It is also employed in the polymer industry for the synthesis of high-performance polymers and in the semiconductor industry for the production of organic semiconductors. Additionally, it is used in the sensor industry for developing highly sensitive and selective sensors.

What precautions should be taken when handling (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate (CAS: 361342-51-0)?

When handling (R)-3,3'-Bis(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate, it is essential to wear appropriate personal protective equipment (PPE), including gloves, safety goggles, and a lab coat. The compound should be handled in a well-ventilated fume hood to minimize inhalation risks. In case of skin contact, immediately wash the affected area with soap and water. If ingested, seek medical attention immediately. Always refer to the Safety Data Sheet (SDS) for detailed safety information and guidelines.

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