Lithium triethyl(hydrido)borate(1-)

Basic Information

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CAS Number

22560-16-3

Molecular Formula

C6H16BLi

Molecular Weight

105 g/mol

Basic Physical Properties

Melting Point

66-67° (Binger); mp 78-83° (dec) (Brown, 1977)

Solubility

Miscible with tetrahydrofuran and benzene.

SMILES

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[Li+].[B-](CC)(CC)CC

InChI

InChI=1S/C6H16B.Li/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1

InChIKey

WCJAYABJWDIZAJ-UHFFFAOYSA-N

LogP

2.54090

Complexity

Safety Information

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GHS Hazard Pictograms

H225

H260

H314

H335

Hazard Statement

H225 Highly Flammable liquid and vapor
Flammable liquids

H260 In contact with water releases flammable gases which may ignite spontaneously
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases

H314 Causes severe skin burns and eye damage
Skin corrosion/irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Hazard Class

Class 4.3 Class 4.3

Sensitiveness

Air & Moisture Sensitive

Synonyms & References

English

lithium triethyl boron
DTXSID10897726
AMCNGINELBODDW-UHFFFAOYSA-N
22560-16-3
Super-Hydride
SUPER-H
AMY14847
BORATE(1-), TRIETHYLHYDRO-, LITHIUM (1:1), (T-4)-
LITHIUM TRIETHYLHYDROBORATE(1-)
L0190
EINECS 245-076-8
Q1ML638JFD
FT-0689125
LITHIUM TRIETHYLBOROHYDRIDE [MI]
AKOS009156531
Super Hydride
Lithium triethylhydroborate
Lithium triethylhydridoborate, 1M in THF, packaged under Argon in resealable ChemSeal bottles
Lithium triethylborohydride
Superhydride
MFCD00011703
UNII-Q1ML638JFD
LITHIUM HYDROTRIETHYLBORATE(1-)
LITHIUM TRIETHYLBOROHYDRIDE 1M SOLUTION IN THF
Lithium triethylborohydride, 1.0 M solution in THF, SpcSeal
1.0 M solution in THF , MkSeal
Li[B(Et)3H]
Lithium borohydride thiethyl
Lithium triethylborohydride [1 M solution in THF]
lithium triethylborohydride solution
LithiuM triethylborohydride, 1M in THF

MDL Number

MFCD00011703

FAQ

What are the physical and chemical properties of Lithium triethyl(hydrido)borate(1-) (CAS: 22560-16-3)?

Lithium triethyl(hydrido)borate(1-) is a colorless to white crystalline solid with a molecular weight of approximately 110.17 g/mol. It has good solubility in organic solvents like ethers and poor solubility in water. It is highly reactive, particularly with acids and moisture, making it sensitive to environmental factors.

How is Lithium triethyl(hydrido)borate(1-) (CAS: 22560-16-3) typically synthesized?

Lithium triethyl(hydrido)borate(1-) is typically synthesized by reacting lithium hydride with triethylborane in the presence of an inert solvent. The process involves careful control of temperature and stirring to ensure a high yield and selectivity of the product.

What industries use Lithium triethyl(hydrido)borate(1-) (CAS: 22560-16-3)?

Lithium triethyl(hydrido)borate(1-) is used in various industries, including pharmaceuticals for organic synthesis, polymers for functional additives, and sensors for catalytic detection. It also finds applications in the synthesis of semiconductors and other materials where its reactivity and stability are advantageous.

What precautions should be taken when handling Lithium triethyl(hydrido)borate(1-) (CAS: 22560-16-3)?

When handling Lithium triethyl(hydrido)borate(1-), it is essential to wear appropriate personal protective equipment (PPE) such as gloves and safety goggles. Work should be done in a fume hood to minimize exposure. Spills should be cleaned up carefully, and the product should be stored in a cool, dry place away from moisture and acids. Always refer to the safety data sheet (SDS) for detailed handling instructions.