Hydridotetrakis(triphenylphosphine)rhodium(I)

Basic Information

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CAS Number

18284-36-1

Molecular Formula

C72H60P4Rh

Molecular Weight

1152 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Basic Physical Properties

Melting Point

140-146 ºC

Boiling Point

No data available

Solubility

Soluble in chloroform, toluene

SMILES

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C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Rh]

InChI

InChI=1S/4C18H15P.Rh/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChIKey

IGTVAJJAPJKARK-UHFFFAOYSA-N

LogP

13.776699999999977

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

202

Safety Information

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GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Air Sensitive

Synonyms & References

English

D81947
MFCD16876684
25869-38-9
YCA46885
AKOS025310731
Hydridotetrakis(triphenylphosphine)rhodium(I)
HRh(PPh3)4
DTXSID90475127
Rhodium, tetrakis(triphenylphosphine)-
18284-36-1
rhodium;triphenylphosphane
hydridotetrakis(triphenylphosphine)-rhodium(I)
Hydridotetrakis (triphenylphosphine) Rhodium (1)
Sodium Hexach, loro Iridate, (II, I) Hy, , drate
HRh(PPh3)4 (Tetrakis(triphenylphosphine)rhodium hydride
HRh(PPh3)4 Tetrakis(triphenylphosphine)rhodium hydride
Tetrakis(triphenylphosphine)rhodium(I) Hydride
Hydridotetrakis(triphenylphosphine)rhodium
Hydrogen tetrakis(triphenyl phosphine)rhodium
Hydrotetrakis(triphenylphosphine)rhodium
Tetrakis(triphenylphosphine)rhodium hydride
rhodium(I)
Hydridotetrakis(triphenylphosphine)
Hydrido tetra(triphenylphosphine)rhodium
HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I)
Hydridotetrakis(trip
Hydridotetrakis(triphenylphosphine)rhodium(I), Rh 8.9% min
HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

MDL Number

MFCD00015867

FAQ

What is Hydridotetrakis(triphenylphosphine)rhodium(I) (CAS: 18284-36-1)?

Hydridotetrakis(triphenylphosphine)rhodium(I) is a rhodium complex with a chemical formula of Rh(PPh3)4H. It is a solid, dark brown to black, and is used as a catalyst in various chemical reactions.

What are the main uses of Hydridotetrakis(triphenylphosphine)rhodium(I) (CAS: 18284-36-1)?

Hydridotetrakis(triphenylphosphine)rhodium(I) is primarily used as a catalyst in hydrogenation reactions, organometallic synthesis, and in the industry for producing various organic compounds such as olefins and alcohols.

Is Hydridotetrakis(triphenylphosphine)rhodium(I) (CAS: 18284-36-1) safe?

Hydridotetrakis(triphenylphosphine)rhodium(I) is generally safe under normal handling conditions. However, it should be used with caution as it is a reactive compound. It is important to avoid inhalation, ingestion, and contact with skin or eyes. Proper ventilation and protective equipment are recommended.

How should Hydridotetrakis(triphenylphosphine)rhodium(I) (CAS: 18284-36-1) be stored?

Hydridotetrakis(triphenylphosphine)rhodium(I) should be stored in a cool, dry place, protected from moisture and light. It should be kept in a tightly sealed container to prevent degradation and ensure safety. Temperature should be maintained below room temperature to minimize reactivity. Avoid exposure to heat and direct sunlight.