Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-)

Basic Information

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CAS Number

17476-04-9

Molecular Formula

C12H28AlLiO3

Molecular Weight

254.27 g/mol

EINECS

241-490-8

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Hydrocarbons

Basic Physical Properties

Melting Point

300-319 °C (dec.)

Boiling Point

66°C (THF)

Density

0.942 g/mL at 25 °C

Water Solubility

Reacts with water.

Flash Point

95 °F

Vapor Pressure

No data available

SMILES

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[Li+].CC(C)(C)O[AlH-](OC(C)(C)C)OC(C)(C)C

InChI

InChI=1S/3C4H9O.Al.Li.H/c3*1-4(2,3)5;;;/h3*1-3H3;;;/q3*-1;+2;+1;

InChIKey

BYBIDFZFKATBFH-UHFFFAOYSA-N

LogP

3.79740

Complexity

25.1

Safety Information

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GHS Hazard Pictograms

H260

H314

Hazard Statement

H260 In contact with water releases flammable gases which may ignite spontaneously
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases

H314 Causes severe skin burns and eye damage
Skin corrosion/irritation

Hazard Class

Class 4.3 Class 4.3

Stability

稳定的。与醇类不相容。与水剧烈反应。高度易燃。

Sensitiveness

Air & Moisture Sensitive

Synonyms & References

English

Lithium hydridotris(tert-butoxy)aluminate, nominally 1M in THF, packaged under Argon in resealable ChemSealTM bottle
Lithium hydridotris(tert-butoxy)aluminate, 90% min
LTTBA
LITHIUM TRI-T-BUTOXYALUMINOHYDRIDE
LITHIUM TRI-(T-BUTOXY)-ALUMINUM HYDRIDE
LITHIUM TRI-TERT-BUTOXYALUMINIUM HYDRIDE
LITHIUM TRI-TERT-BUTOXYALUMINOHYDRIDE
LITHIUM TRI-TERT-BUTOXYALUMINUM HYDRIDE
Lithium tri-tert-butoxyaluminohydride
lithium aluminum-tri-tert-butoxyhydride
aluminium lithium tri-tert-butoxide hydride
Lithiumaluminiumtritertbutoxyhydride
Lithium tri-t-butoxyaluminohydride
Lithium tri-tert-butoxyaluminum hydride
Lithium tri-(tert)-butoxyaluminum hydride
Lithium tri(tert-butoxy)aluminum hydride
Lithium tri-t-butoxyaluminohydride, ~1.0M in THF
Lithium tri-tert-butoxyaluminum hydride (LTBA)
Lithium Tri-tert-butoxyaluminum Hydride Solution
Aluminiumlithiumtri-tert-butoxidhydrid
Lithium tri-t-butoxyaluminium Hydride
Lithium tri-tert-but
Lithium tri-tert-butoxyaluminum
LithiuM tri-tert-butoxyaluMinuM hydride, noMinally 1M in THF, packaged under Argon in resealable CheMSeal^t bottles
lithiumtri-tert-butoxyhydroaluminate
Lithium Tri-tert-butoxyalyminium Hydride
LTBA
Aluminate(1-),hydrotris(2-methyl-2-propanolato)-, lithium, (T-4)- (9CI)
Aluminate(1-),tri-tert-butoxyhydro-, lithium (8CI)
Lithium hydrotri-tert-butoxyaluminate(7CI)
2-Propanol, 2-methyl-, aluminum complex

MDL Number

MFCD00011532

EC Number

241-490-8

Customs Code

29055900

FAQ

What regulatory guidelines apply to Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9)?

Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) is subject to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), which includes hazard communication labels and safety data sheets. It also falls under the European Chemicals Agency (ECHA) REACH regulations for the registration, evaluation, authorization, and restriction of chemicals. FDA and EPA have specific requirements concerning the handling and disposal of this compound due to its potential health and environmental impacts.

Are there alternatives to Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) in synthesis?

In synthesis, alternatives to Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) include other lithium aluminates, such as lithium diisopropylamide (LDA), and various organometallic reagents. These alternatives offer different reactivity profiles and are used depending on the specific chemical needs and desired outcomes of the synthesis.

What is the market or research trend for Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9)?

The market for Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) is primarily driven by its applications in organic synthesis, particularly in the preparation of organolithium compounds and as a catalyst in various chemical reactions. Research trends include the development of more sustainable and environmentally friendly synthesis methods and the exploration of its use in new functional materials and technologies.

How should waste containing Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) be handled?

Waste containing Lithium hydrido[tris(2-methyl-2-propanolato)]aluminate(1-) (CAS: 17476-04-9) should be collected in appropriate containers and disposed of through professional waste disposal services. Proper incineration or neutralization processes should be employed to minimize environmental impact. Environmental protection guidelines, such as those provided by the Environmental Protection Agency (EPA), must be followed to ensure safe and compliant disposal.