1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) | CAS No. 15629-92-2

1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1)

Basic Information

CAS Number

15629-92-2

Molecular Formula

C27H26Cl2NiP2

Molecular Weight

542 g/mol

AD

Basic Physical Properties

Melting Point

213 °C (dec.)

Flash Point

291.5℃

C1=CC=C(C=C1)P(CCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Ni]Cl

InChI

InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChIKey

ZBQUMMFUJLOTQC-UHFFFAOYSA-L

LogP

7.02130

Complexity

353

Safety Information

View Safety Information

GHS Hazard Pictograms

H315H315
H317H317
H319H319
H334H334
H335H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation
H317 May cause an allergic skin reaction
Sensitization, Skin
H319 Causes serious eye irritation
Serious eye damage/eye irritation
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
Sensitization, respiratory
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

对湿度敏感

Synonyms & References

English

  • J-502709
  • SY002264
  • dichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphane
  • (1,3-dppp)NiCl2
  • C27H26Cl2NiP2
  • AKOS005259144
  • 1,3-Bis(diphenylphosphino)propane nickel(II)chloride
  • [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
  • 1,3-Bis(diphenylphosphino)propane-nickel (II) chloride
  • 1,3-bis(diphenylphosphino)propanenickel(ii) chloride
  • [3-(DIPHENYLPHOSPHANYL)PROPYL]DIPHENYLPHOSPHANE; NICKEL CHLORIDE
  • 1,3-Bis(diphenylphosphino)propane nickel(II) chloride
  • [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
  • MFCD00015318
  • FD14035
  • [1,3-Bis(diphenylphosphino)propane] dichloronickel (II)
  • 1,3-Bis(diphenylphosphino)propane nickel (II) chloride
  • SCHEMBL6328
  • Ni(dppp)Cl2
  • 15629-92-2
  • AC-4982
  • mononickel(II) mono(propane-1,3-diylbis(diphenylphosphonium)) dichloride
  • [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
  • [1,3-Bis(diphenylphosphino)propane] dichloronickel
  • dichloro[1,3-Bis(diphenylphosphino)propane]nickel
  • Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II)
  • 3-Diphenylphosphanylpropyl(diphenyl)phosphane;nickel;dihydrochloride

MDL Number

MFCD00015318

FAQ

What is 1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2)?

1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1), with CAS number 15629-92-2, is a coordination compound containing a nickel atom bonded to two diphenylphosphine groups via a 1,3-propanediyl linker. It is commonly used as a catalyst precursor in organic synthesis due to its ability to facilitate various chemical reactions. The compound exhibits moderate solubility in organic solvents and is typically a yellow solid at room temperature.

What are the main uses of 1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2)?

1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2) is primarily used in catalytic applications, especially in cross-coupling reactions and hydrogenation processes. It serves as a valuable precursor in pharmaceutical and fine chemical synthesis. Additionally, it is used in research for studying transition metal complexes and their reactivity in various chemical environments.

Is 1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2) safe?

1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2) should be handled with care. It is generally considered non-toxic in small quantities but may cause irritation if inhaled or contacted with skin. Safety standards recommend using appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. It is important to follow standard laboratory safety protocols when working with this compound.

How should 1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2) be stored?

1,3-Propanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 15629-92-2) should be stored in a sealed container in a cool, dry, and dark place. It is stable under normal storage conditions but should be kept away from moisture and incompatible materials. Proper labeling and storage in a well-ventilated area are recommended to ensure safety and maintain chemical integrity.

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