Carbonylchloro bis(triphenylphosphine)iridium(I)

Basic Information

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CAS Number

14871-41-1

Molecular Formula

C37H32ClIrOP2-

Molecular Weight

781.27 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Carboxylic Acids

Fine Chemicals Dyes and Pigments Organic Dyes

Fine Chemicals Surfactants Anionic Surfactants

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

215°C

Solubility

Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol

SMILES

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C=O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Ir]

InChI

InChI=1S/2C18H15P.CHO.ClH.Ir/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;1H;1H;/q;;;;+1/p-1

InChIKey

KMVALWICXMGTQO-UHFFFAOYSA-M

LogP

7.302500000000008

Topological Polar Surface Area

17.07 Å²

Hydrogen Bond Donor/Acceptor

0 / 1

Complexity

204

Safety Information

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GHS Hazard Pictograms

H331

H302

H312

Hazard Statement

H331 Toxic if inhaled
Acute toxicity, inhalation

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

Hazard Class

Class 6.1 Class 6.1

Synonyms & References

English

Carbonylchlorobis(triphenylphosphine)iridium(I)
MFCD00009590
Chlorocarbonylbis(triphenylphosphine)iridium(I)
Carbonylchloro bis(triphenylphosphine)iridium(I)
AKOS022186674
formaldehyde;iridium;triphenylphosphane;chloride
14871-41-1
Bis(triphenylphosphine)iridium(I) carbonyl chloride
CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE
Carbonylbis(triphenylphosphine)iridium(I)chloride
Bis(triphenylphosphine)iridiumcarbonyl chloride
carbonylchlorobis(triphenylphosphine)-iridium(I),
Bis(triphenylphosphine)iridium(I) Carbonyl Chloride
Vaska's Catalyst
iridium(I)
VASKA'S COMPLEX
IrCl(CO)(PPh3)2
Carbonylchloro bis(triphenylphosphine)
carbonylchlorobis(triphenylphosphine)iridium
carbonylchlorobis(triphenylphosphine)-iridiu
Carbonylchlorobis(triphenylphosphine)iridium(Ⅰ)
Carbonylbis(triphenylphosphine)iridium(I) Chloride
vaska's catalyst
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE

MDL Number

MFCD00009590

FAQ

What regulatory guidelines apply to Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1)?

Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1) is regulated under GHS (Globally Harmonized System of Classification and Labeling of Chemicals) for hazardous materials, and is also subject to REACH regulations for the registration, evaluation, authorization, and restriction of chemicals in the European Union. In the United States, the EPA and FDA have specific regulations for the handling and use of this compound. It is important to adhere to local and international laws when dealing with this substance.

Are there alternatives to Carbonylchloro bis(triphenylphosphine)iridium(I) in synthesis?

There are several alternatives to Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1) in synthesis, including other iridium complexes and different phosphine ligands. For instance, bis(triphenylphosphine)iridium(III) dichloride and carbonylchloro bis(triphenylphosphine)iridium(III) are often used as alternatives depending on the specific reaction conditions and desired outcomes.

What is the market or research trend for Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1)?

The market for Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1) is currently growing due to its application in catalytic reactions, particularly in organic synthesis. Research trends are focusing on its use in asymmetric catalysis and the development of new iridium complexes for various synthetic transformations. The compound is also gaining attention in academic and industrial settings for its versatile catalytic properties.

How should waste containing Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1) be handled?

Waste containing Carbonylchloro bis(triphenylphosphine)iridium(I) (CAS: 14871-41-1) should be collected in appropriate containers and disposed of through professional waste disposal services. Incineration is a common method for disposal, but ensure it is done in an enclosed system to prevent the release of harmful gases. Environmental protection precautions include the use of personal protective equipment and adherence to local waste management regulations to minimize environmental impact.