Chlororhodium - triphenylphosphine (1:3)

Basic Information

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CAS Number

14694-95-2

Molecular Formula

C54H45ClP3Rh

Molecular Weight

925.24 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

245-250 ºC

Boiling Point

>170°C

Flash Point

181.7℃

Solubility

Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution

SMILES

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C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]

InChI

InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChIKey

IXAYKDDZKIZSPV-UHFFFAOYSA-M

LogP

11.021399999999991

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

202

Safety Information

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GHS Hazard Pictograms

H413

Hazard Statement

H413 May cause long lasting harmful effects to aquatic life
Hazardous to the aquatic environment, long-term hazard

Sensitiveness

air sensitive

Synonyms & References

English

0FV534BKEV
Tris(triphenylphosphine)rhodium monochloride
Tris(triphenylphosphine)rhodiu
Tris(triphenylphosphine)rhodium (I) chloride
AC-1011
Chlorotris (triphenylphosphine)rhodium(I)
14694-95-2
I10267
tris-(triphenylphosphine)rhodium(I)chloride
AKOS015964328
MFCD00010016
rhodium;triphenylphosphane;chloride
Chlorotris(triphenylphosphine)rhodium
16592-65-7
(SP-4-2)-Chlorotris(triphenylphosphine)rhodium
tris-(triphenylphosphine)chlororhodium
WILKINSON'S CATALYST [MI]
chlorotris(triphenylphosphine) rhodium (i)
Q27236720
Wilkinson Catalyst
Chlorotris(triphenylphosphine)rhodium(I)
Tris(triphenylphosphine)chlororhodium
Tris(triphenylphosphine)rhodium chloride
tris(triphenylphosphine)-rhodium(i) chloride
tris(triphenylphosphine)-rhodium (I) chloride
A808571
DTXSID30893902
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE
tris(triphenylphosphine)rhodium(i)chloride
Wilkinson's catalyst
Tris(triphenylphosphino)chlororhodium

MDL Number

MFCD00010016

Customs Code

2942000000

FAQ

What is Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2)?

Chlororhodium - triphenylphosphine (1:3), with the CAS number 14694-95-2, is a coordination compound consisting of a rhodium atom bonded to one chloride ligand and three triphenylphosphine molecules. It is commonly used as a catalyst in organic chemistry due to its ability to facilitate various reactions, including hydrogenation and coupling processes. The compound is typically a yellow solid and exhibits moderate solubility in organic solvents.

What are the main uses of Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2)?

Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2) is primarily used as a catalyst in pharmaceutical and industrial applications. It plays a key role in catalytic hydrogenation, carbonylations, and cross-coupling reactions. Additionally, it is used in research settings for the synthesis of complex organic molecules and in the development of new chemical processes. Its catalytic efficiency and selectivity make it valuable in both academic and commercial contexts.

Is Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2) safe?

Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2) is considered hazardous and requires careful handling. It may cause skin and eye irritation, and inhalation can be harmful. Safety standards recommend using personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Proper ventilation and adherence to laboratory safety protocols are essential when working with this compound to minimize exposure risks.

How should Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2) be stored?

Chlororhodium - triphenylphosphine (1:3) (CAS: 14694-95-2) should be stored in a cool, dry, and dark place, away from moisture and air. It is best kept in a sealed container made of inert material such as glass or Teflon to prevent degradation. Storage at temperatures below 25°C and in a low-humidity environment is recommended to maintain stability and prolong shelf life.