1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1)

Basic Information

View in Editor

CAS Number

14647-23-5

Molecular Formula

C26H24Cl2NiP2

Molecular Weight

528 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

263-265 °C

Boiling Point

514.8°Cat760mmHg

Flash Point

281.7°C

SMILES

View in Editor

C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Cl-].[Ni+2]

InChI

InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChIKey

XXECWTBMGGXMKP-UHFFFAOYSA-L

LogP

-0.73980

Complexity

336

Safety Information

View Safety Information

GHS Hazard Pictograms

H302

H312

H315

H319

H332

H334

H335

H350

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H332 Harmful if inhaled
Acute toxicity, inhalation

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
Sensitization, respiratory

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

H350 May cause cancer
Carcinogenicity

Synonyms & References

English

AC-4981
2-diphenylphosphanylethyl(diphenyl)phosphane;nickel(2+);dichloride
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
AKOS015915194
nickel(2+) ion [2-(diphenylphosphanyl)ethyl]diphenylphosphane dichloride
CS-W002089
1,2-Ethylenebis(diphenylphosphine)nickel dichloride
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
DS-0824
B2225
Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
14647-23-5
1,2-Bis(diphenylphosphinoethane)nickel(II) chloride
AMY19685
BCP22511
DTXSID60432121
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel
[Bis(diphenylphosphino)ethane]dichloronickel
2-diphenylphosphanylethyl(diphenyl)phosphane,nickel(2+),dichloride
Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
[1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride
dppeNiCl2
Nickel,dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']-, (SP-4-2)-
Nickel,dichloro[ethylenebis[diphenylphosphine]]- (7CI)
Nickel,dichloro[ethylenebis[diphenylphosphine]]-, cis- (8CI)
(Bis(diphenylphosphino)ethane)dichloronickel
1,2-Bis(diphenylphosphino)ethanenickel dichloride
Dichloro[1,2-bis(diphenylphosphino)ethane]nickel
Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel

MDL Number

MFCD00013313

FAQ

What is 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 14647-23-5)?

1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1), with CAS number 14647-23-5, is a nickel complex featuring two diphenylphosphine ligands bridged by an ethane-1,2-diyl group and two chloride ions. It is typically a solid with coordination properties, used as a precursor in catalytic applications. The compound exhibits reactivity in organic synthesis and is sensitive to moisture and air.

What are the main uses of 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 14647-23-5)?

This compound is primarily used in pharmaceutical synthesis as a catalyst precursor, enabling efficient reactions in drug development. It also serves in industrial chemistry for polymerization processes and in research for studying transition metal complexes. Its applications include organometallic chemistry and materials science, where it facilitates the creation of functional compounds and nanomaterials.

Is 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 14647-23-5) safe?

Handling 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) requires caution due to potential toxicity from nickel and phosphine ligands. It may cause skin or respiratory irritation and should be used in well-ventilated areas with protective gloves and goggles. Safety standards emphasize avoiding exposure to moisture and following OSHA guidelines for chemical handling.

How should 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 14647-23-5) be stored?

Store 1,2-Ethanediylbis(diphenylphosphine) - dichloronickel (1:1) (CAS: 14647-23-5) in a cool, dry place away from light and moisture. Use airtight, inert containers to prevent degradation. Maintain storage conditions below 25°C and ensure humidity levels remain low. Avoid contact with air and keep it in a chemically inert environment to ensure stability and safety.