Nickel(2+) chloride - triphenylphosphine (1:2:2)

Basic Information

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CAS Number

14264-16-5

Molecular Formula

C36H30Cl2NiP2

Molecular Weight

656.2 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

250 °C (dec.)

Boiling Point

360ºCat 760 mmHg

Flash Point

181.7ºC

SMILES

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C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl

InChI

InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey

ZBRJXVVKPBZPAN-UHFFFAOYSA-L

LogP

7.7307000000000095

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

204

Safety Information

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GHS Hazard Pictograms

H317

H350

Hazard Statement

H317 May cause an allergic skin reaction
Sensitization, Skin

H350 May cause cancer
Carcinogenicity

Hazard Class

Class 6.1(b) Class 6.1(b)

Sensitiveness

Hygroscopic

Synonyms & References

English

dichloronickel; triphenylphosphane
Dichlorobis(triphenylphosphine)nickel(II)
Bis(triphenylphosphine)nickel(II) dichloride, synthesis grade
Bis(triphenylphosphine)nickel(II) dichloride
NiCl2(PPh3)2
Bis(triphenylphosphine)nickel(II)chloride
MFCD00009592
AKOS025402105
AC-4984
Bis(triphenylphosphine)nickel(II) chloride, 99.99% trace metals basis
NSC625181
Bis(triphenylphosphine)nickel(II) dichloride, 99.99% trace metals basis
FD14036
SCHEMBL164931
dichloronickel;triphenylphosphane
14264-16-5
MONONICKEL(II) BIS(TRIPHENYLPHOSPHONIUM) DICHLORIDE
Bis(triphenylphosphine)nickel(II) chloride
BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE
DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL
DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE
NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE
Bis(tri-N-butylphosphine)dichloronickel
bis(triphenylphosphine)dichloro-nicke
Bis(triphenylphosphine)dichloronickel
Bis(triphenylphosphine)nickel dichloride
Dichlorobis(triphenyIphosphine)-nickel(II)
dichlorobis(triphenylphosphine)-nicke

MDL Number

MFCD00009592

Customs Code

29310095

FAQ

What is Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5)?

Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) is a coordination compound combining nickel(II) ions with chloride ligands and triphenylphosphine. It typically appears as a solid with a yellowish color, known for its catalytic properties and applications in organic synthesis. The compound is hygroscopic and soluble in polar solvents, making it a versatile reagent in chemical reactions involving metal-ligand interactions.

What are the main uses of Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5)?

Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) is widely used in pharmaceuticals for catalysts in drug synthesis, in industrial processes for polymerization reactions, and in research for organometallic chemistry. It also serves as a reagent in coupling reactions and as a precursor for other nickel compounds. Its unique structure makes it valuable in applications requiring controlled redox activity and ligand coordination.

Is Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) safe?

Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) requires careful handling due to potential toxicity from nickel exposure and the flammability of triphenylphosphine. Prolonged contact may cause skin or respiratory irritation. Safety standards recommend using personal protective equipment (PPE), ensuring proper ventilation, and avoiding ingestion. Always follow OSHA guidelines when working with this compound.

How should Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) be stored?

Nickel(2+) chloride - triphenylphosphine (1:2:2) (CAS: 14264-16-5) should be stored in a cool, dry place (ideally below 25°C), away from light and moisture. Keep in a sealed, airtight container, preferably made of glass or polyethylene, to prevent degradation. Avoid exposure to humid environments and ensure storage in a well-ventilated area to maintain stability and safety.