1-Propenylmagnesium bromide

Basic Information

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CAS Number

14092-04-7

Molecular Formula

C3H5BrMg

Molecular Weight

145.28 g/mol

Chemical Classification

Water Treatment Chemicals Disinfectants Chlorine Compounds

Basic Physical Properties

Boiling Point

65 °C

SMILES

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CC=[CH-].[Mg+2].[Br-]

InChI

InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h1,3H,2H3;1H;/q-1;;+2/p-1

InChIKey

WQMNNHNWITXOAH-UHFFFAOYSA-M

LogP

1.91490

Complexity

14.4

Safety Information

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Hazard Statement

H225 Highly Flammable liquid and vapor
Flammable liquids

H260 In contact with water releases flammable gases which may ignite spontaneously
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases

H302 Harmful if swallowed
Acute toxicity, oral

H314 Causes severe skin burns and eye damage
Skin corrosion/irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

H351 Suspected of causing cancer
Carcinogenicity

Synonyms & References

English

Magnesium, bromo-1-propenyl-
(E)-prop-1-enylmagnesium bromide
prop-1-en-1-ylmagnesium bromide
13154-14-8
propenyl magnesium bromide
(z)-prop-1-enylmagnesium bromide
HHNLJRLNDSEYOX-UHFFFAOYSA-M
(Z-propenylmagnesium)bromide
(e)-propenylmagnesium bromide
MFCD00209610
Magnesium, bromo-(1Z)-1-propenyl-
14092-04-7
propenylmagnesium bromide
prop-1-enylmagnesium bromide
1-Propenylmagnesium bromide, 0.5M (7.65% w/w) in THF
(E)-Prop-1-en-1-ylmagnesium bromide
Magnesium, bromo-1-propenyl- (9CI)
trans-1-propenyl-magnesium bromide
AKOS024262735
SCHEMBL262691
1-propenyl magnesium bromide
DTXSID901309034
1-PROPENYLMAGNESIUM BROMIDE
1-Propenylmagnesium bromide, 0.5 M solution in THF, SpcSeal
Magnesium,bromo-1-propenyl- (9CI)
(prop-1-enyl)magnesium bromide
1-Propenylbromomagnesium
1-Propenylmagnesium bromide solution
1-Propenylmagnesium bromide,0.5M solution in THF,AcroSeal
2-propenylmagnesiumbromide
Bromo(1-propenyl) magnesium

MDL Number

MFCD00209610

Customs Code

29319090

FAQ

What are the physical and chemical properties of 1-Propenylmagnesium bromide (CAS: 14092-04-7)?

1-Propenylmagnesium bromide (CAS: 14092-04-7) is a colorless to pale yellow, flammable liquid with a molecular weight of 100.12 g/mol. It has a low solubility in water but is highly soluble in polar solvents such as ethers and alcohols. The compound is highly reactive, acting as a strong nucleophile in electrophilic addition reactions and nucleophilic substitution reactions.

How is 1-Propenylmagnesium bromide (CAS: 14092-04-7) typically synthesized?

1-Propenylmagnesium bromide is typically synthesized by reacting 1-propene with magnesium in the presence of bromine. The reaction is conducted under anhydrous conditions and in an inert solvent such as diethyl ether. The yield is generally high, and the reaction is highly selective, producing 1-Propenylmagnesium bromide with good purity.

What industries use 1-Propenylmagnesium bromide (CAS: 14092-04-7)?

1-Propenylmagnesium bromide (CAS: 14092-04-7) is primarily used in the pharmaceutical industry for the synthesis of complex organic molecules, and in the polymer industry for the production of specific types of polymers. It also finds applications in the electronics industry for the fabrication of sensors and semiconductors.

What precautions should be taken when handling 1-Propenylmagnesium bromide (CAS: 14092-04-7)?

When handling 1-Propenylmagnesium bromide (CAS: 14092-04-7), it is essential to wear appropriate personal protective equipment (PPE), including gloves, goggles, and a lab coat. The compound should be stored in a cool, dry place, away from heat sources and oxidizers. Use a fume hood when mixing or using the compound to minimize exposure. In the event of a spill, consult the Material Safety Data Sheet (MSDS) for proper cleanup procedures.