2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1) | CAS No. 135620-04-1

2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1)

Basic Information

CAS Number

135620-04-1

Molecular Formula

C36H54Cl3MnN2O2

Molecular Weight

708.14 g/mol

AD

Basic Physical Properties

Melting Point

330-332 °C

CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC2CCCCC2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.[Cl-].[Cl-].[Cl-].[Mn+3]

InChI

InChI=1S/C36H54N2O2.3ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;;;/h17-22,29-30,39-40H,13-16H2,1-12H3;3*1H;/q;;;;+3/p-3/b37-21+,38-22+;;;;/t29-,30-;;;;/m0..../s1

InChIKey

VGAJDQCIDNCJQC-JINVCYSXSA-K

LogP

11.202999999999985

Topological Polar Surface Area

65.18 Ų

Hydrogen Bond Donor/Acceptor

2 / 4

Complexity

793

Safety Information

View Safety Information

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation
H319 Causes serious eye irritation
Serious eye damage/eye irritation
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

  • D77760
  • (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride
  • MFCD02101663
  • (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • 135620-04-1
  • (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]Mn(III) chloride
  • (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • (S,S)-Jacobsen's catalyst manganese(III) chloride complex
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride
  • (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chlorideSalen
  • (1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
  • (S,S)-(+)N,N‘-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Jacobsen catalyst
  • JACOBSEN'S CATALYST

MDL Number

MFCD02101663

Customs Code

29310099

FAQ

What are the physical and chemical properties of 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1) (CAS: 135620-04-1)?

This compound has a crystalline form at room temperature and a molecular weight of approximately 1210.2 g/mol. It has low water solubility and is partially soluble in organic solvents. It exhibits limited reactivity under normal conditions but can undergo coordination chemistry reactions with transition metals. The compound is stable under typical laboratory conditions but should be stored in a cool, dry environment away from moisture and direct sunlight.

How is 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1) (CAS: 135620-04-1) typically synthesized?

This compound is typically synthesized through a multistep process involving the reaction of 4,6-bis(2-methyl-2-propanyl)phenol with 1,2-cyclohexanediamine, followed by coordination with trichloromanganese. The synthesis involves careful control of temperature and pH to ensure high yield and selectivity. Commonly used catalysts include strong acids and bases, and the reaction mixture is typically monitored using NMR spectroscopy.

What industries use 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1) (CAS: 135620-04-1)?

This compound is primarily used in the pharmaceutical industry for the synthesis of various organic compounds. It is also utilized in the polymer industry for functionalization of polymer surfaces and in the semiconductor industry for doping applications. Additionally, it has potential applications in the development of sensors due to its reactivity and coordination properties.

What precautions should be taken when handling 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1) (CAS: 135620-04-1)?

When handling this compound, it is essential to wear appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. The substance should be handled in a fume hood to prevent inhalation and skin contact. Spills should be cleaned up carefully using appropriate absorbent materials. It is recommended to refer to the Safety Data Sheet (SDS) for detailed handling and disposal information. Proper storage in a cool, dry environment is necessary to maintain stability.

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