(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

Basic Information

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CAS Number

135616-36-3

Molecular Formula

C36H54N2O2

Molecular Weight

546.8 g/mol

Chemical Classification

Fine Chemicals Dyes and Pigments Organic Dyes

Basic Physical Properties

Melting Point

203-206 °C

Boiling Point

646.3 ℃ at 760 mmHg

Flash Point

115.2℃

Refractive Index

1.5300 (estimate)

Specific Rotation

+305° (c 1, CH2Cl2)

SMILES

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CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=NC2CCCCC2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O

InChI

InChI=1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/t29-,30-/m0/s1

InChIKey

FYNXDGNCEBQLGC-KYJUHHDHSA-N

LogP

9.13700

Complexity

793

Safety Information

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GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

(S,S)-(+)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexane
AC8931
2,4-ditert-butyl-6-[(e)-[(1s,2s)-2-[(e)-(3,5-ditert-butyl-2-hydroxy-phenyl)methyleneamino]cyclohexyl]iminomethyl]phenol
AKOS030238937
(1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine, 98%
135616-36-3
SCHEMBL1195690
2,4-DI-TERT-BUTYL-6-({[(1S,2S)-2-{[(3,5-DI-TERT-BUTYL-2-HYDROXYPHENYL)METHYLIDENE]AMINO}CYCLOHEXYL]IMINO}METHYL)PHENOL
SCHEMBL17215329
(S,S)-(+)-N,N?-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
2,2'-[(1S,2S)-1,2-Cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenol
CS-W011465
AS-72909
GEO-03070
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
FYNXDGNCEBQLGC-KYJUHHDHSA-N
DTXSID201115810
MFCD00191801
(S,s)-(+)-N,N'-bis(3,5-di-t-butylsalicylidene)cyclohexane-1,2-diamine
2,4-ditert-butyl-6-[[(1S,2S)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol
AKOS015904323
J-006736
C36H54N2O2
(S,S)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
2,4-di-t-butyl-6-[(e)-{[(1s,2s)-2-{[(e)-(3,5-di-t-butyl-2-hydroxyphenyl)methylidene]-amino}cyclohexyl]imino}methyl]phenol
B4647
(1S,2S)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene),(S,S)-Jacobsen Ligand
(S,S)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamineSalen
(S,S)-(+)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

MDL Number

MFCD00191801

FAQ

What regulatory guidelines apply to (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3)?

Regulatory guidelines for (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) include GHS classification, which categorizes it as a flammable liquid. Additionally, it must comply with REACH regulations in the EU, ensuring that manufacturers and importers register and assess the substance. FDA guidelines ensure its safety for use in the food and pharmaceutical industries, while EPA regulations oversee its handling and disposal to protect the environment.

Are there alternatives to (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) in synthesis?

There are alternatives to (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) in synthesis, such as other diamines or salicylaldehyde derivatives. Common substitutes include (R,R)-(-)-1,2-cyclohexanediamine and (S,S)-(+)-N,N'-Bis(salicylidene)-1,2-cyclohexanediamine. These alternatives offer similar functional groups and can be used in various chemical reactions depending on the desired outcome.

What is the market or research trend for (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3)?

The market for (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) is growing due to its applications in pharmaceuticals and polymer science. Research trends focus on its properties as a chiral diamine, which are crucial for asymmetric synthesis. Emerging studies also explore its use in drug delivery systems and as a monomer for developing new materials, indicating strong market demand and potential for future innovations.

How should waste containing (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) be handled?

Waste containing (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS: 135616-36-3) should be collected in appropriate containers and stored in a well-ventilated area. For disposal, incineration is a common method, but professional waste disposal services are recommended to ensure compliance with environmental regulations. Proper precautions include the use of personal protective equipment and adherence to safety guidelines to prevent environmental contamination and personal harm.