[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride

Basic Information

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CAS Number

130004-33-0

Molecular Formula

C54H46Cl2P2Ru

Molecular Weight

928.89 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

>100°C

SMILES

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CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl

InChI

InChI=1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChIKey

WNHLGYRPKARUHY-UHFFFAOYSA-L

LogP

13.671319999999973

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

886

Safety Information

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Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Air Sensitive

Synonyms & References

English

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium chloride, purum
MFCD00134456
F16612
SY071536
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
Chloro[(R)-(+)-2,2 inverted exclamation mark -bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthyl](p-cymene)ruthenium(II) Chloride
Dichlororuthenium [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane 1-isopropyl-4-methylbenzene
D97679
AKOS015914587
dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene
SY073011
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
A888798
(R)-RuCl[(p-cymene)(BINAP)]Cl
[RuCl(p-cymene)((S)-binap)]Cl
Chloro[(S)-(-)-2,2 inverted exclamation mark -bis(diphenylphosphino)-1,1 inverted exclamation mark -binaphthyl](p-cymene)ruthenium(II) Chloride
[rucl((r)-binap)(p-cymene)]cl
CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL] (P-CYMENE)RUTHENIUM(II) CHLORIDE
(S)-RuCl[(p-cymene(BINAP)]Cl
145926-28-9
130004-33-0
Ruthenium(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,chloride (1:1)
[RuCl(p-cymene)((S)-binap)]Cl [RuCl(p-cymene)((S)-binap)]Cl
Ruthenium(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-met
Ruthenium(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1...
(S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalenechloro(p-cymene)ruthenium chloride
-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
-bis(diphenylphosphino)-1,1&#039
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl

MDL Number

MFCD00134456

FAQ

What regulatory guidelines apply to [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0)?

The regulatory guidelines for [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) include GHS classification for hazardous chemicals, REACH regulations in the European Union, FDA guidelines for pharmaceutical applications, and EPA regulations for environmental protection. It is essential to comply with local and international regulations to ensure safe handling and use of the compound.

Are there alternatives to [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) in synthesis?

Yes, alternatives to [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) in synthesis include other ruthenium complexes with different ligands. Common alternatives include [1,1'-Bis(diphenylphosphino)ferrocene]ruthenium(II) chloride and [2,2'-Bis(diphenylphosphino)binaphthyl]ruthenium(II) chloride. These alternatives offer similar catalytic properties but may vary in reactivity and selectivity.

What is the market or research trend for [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0)?

The market trend for [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) is driven by its use in catalytic reductions and cross-coupling reactions. Research trends focus on optimizing its performance in organic synthesis and exploring its potential in new applications. The compound is highly valued for its ability to facilitate complex reactions with high selectivity and efficiency.

How should waste containing [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) be handled?

Waste containing [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (CAS: 130004-33-0) should be collected and disposed of according to local regulations. Proper waste management includes neutralizing any reactive components, ensuring safe storage, and consulting with a hazardous waste disposal service for incineration or professional disposal. It is crucial to follow safety guidelines to prevent environmental contamination and ensure worker safety.