Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron

Basic Information

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CAS Number

12150-46-8

Molecular Formula

C34H28FeP2

Molecular Weight

554.39 g/mol

EINECS

640-119-0

Chemical Classification

Fine Chemicals Dyes and Pigments Organic Dyes

Agricultural Chemicals Pesticides Insecticides

Basic Physical Properties

Melting Point

181-182 °C (dec.)

Boiling Point

363.8°Cat760mmHg

Density

1.5270

Water Solubility

Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Flash Point

182.8℃

SMILES

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C1(P(C2=CC=CC2[Fe]C3C=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6)=CC=CC=C1

InChI

InChI=1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

InChIKey

HPXNTHKXCYMIJL-UHFFFAOYSA-N

LogP

7.8191000000000095

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

276

Safety Information

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Hazard Statement

Hazard Class

Class IRRITANT Class IRRITANT

Stability

Stable. Incompatible with strong oxidizers.

Hydrolysis Sensitivity

7: reacts slowly with moisture/water

Sensitiveness

Air Sensitive

Synonyms & References

English

DPPF
1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)
DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE
1,1'-Bis(diphenylphosphiNA)ferrocene
DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine)
1,1-(twophenylphosphine)Er Maotie
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE)
1,1'-bis(diphenyphosphino)ferrocene
1,1'-Bis(diphenylphosphino) ferrocene, Catalyst Grade
1,1μ-Ferrocenebis(diphenylphosphine), 1,1μ-Ferrocenediyl-bis(diphenylphosphine)
1,1’-Bis(diphenylphosphino)ferrocene
1,1-Bis(diphenylphosphino)ferrocene
1,1`-Bis(diphenylphosphino)ferrocene
1,1’-
1,1’-Bis(diphenylphosphino)ferrocene (DPPF)
1,1'-bis(diphenylphosphanyl)ferrocene
1,1'-bis(diphenylphosphino)ferrocene palladium chloride
1'-Bis(diphenylphosphino)ferrocene
Cyclopentadienyldiphenylphosphine
Zirconium ionophore I
1,1'-Ferrocenediyl-bis(diphenylphosphine)
dppf
1,1'-Ferrocenebis(diphenylphosphine)
ferrous;cyclopenta-2,4-dien-1-yl(diphenyl)phosphane(1:2)

MDL Number

MFCD00001422

EC Number

640-119-0

Customs Code

29319090

FAQ

What is Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8)?

Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) is a coordination compound composed of iron and two cyclopentadienyl ligands substituted with diphenylphosphino groups. It is a yellow solid with a molecular formula of C24H26FeP2 and is known for its stability and reactivity in various chemical reactions. This compound is widely used in catalytic processes due to its unique electronic properties.

What are the main uses of Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8)?

Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) is primarily used as a catalyst in organic synthesis, especially in hydrogenation and coupling reactions. It also finds applications in pharmaceutical research, materials science, and industrial chemical processes. Its ability to facilitate selective reactions makes it valuable in the development of new drugs and specialty chemicals.

Is Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) safe?

Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) is generally considered safe when handled properly. However, it should be treated with caution as it may cause irritation if inhaled or contacted with skin. Protective equipment such as gloves, goggles, and a fume hood is recommended. Safety standards emphasize proper storage and handling to prevent exposure and ensure compliance with chemical regulations.

How should Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) be stored?

Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron (CAS: 12150-46-8) should be stored in a cool, dry, and dark place to maintain its stability. It is recommended to keep it in a sealed container away from moisture and air to prevent degradation. Storage conditions should be controlled to ensure optimal performance and safety, typically at temperatures below 25°C and with minimal exposure to light.