(1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1)

Basic Information

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CAS Number

12107-56-1

Molecular Formula

C8H12Cl2Pd

Molecular Weight

285.51 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Hydrocarbons

Basic Physical Properties

Melting Point

210 °C (dec.)

Solubility

Soluble in dichloromethane

SMILES

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C1CC=CCCC=C1.Cl[Pd]Cl

InChI

InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

InChIKey

RRHPTXZOMDSKRS-PHFPKPIQSA-L

LogP

4.049300000000002

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

75.4

Safety Information

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GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Hygroscopic

Synonyms & References

English

AC-18121
AKOS015964034
Dichloro(1,5-cyclooctadiene)palladium( cento)
Palladium, dichloro((1,2,5,6-eta)-1,5-cyclooctadiene)-
Dichloro(1,5-cyclooctadiene)palladium(II), 99%
Dichloro(1,5-cyclooctadiene)palladium
Dichloro(1,5-cyclooctadiene)palladium(II)
Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]-
SCHEMBL502942
Dichloro(cycloocta-1,5-diene)palladium(II), Pd 37.3%
dichloro(1,5-cycloocta-diene)palladium(ii)
(1Z,5Z)-cycloocta-1,5-diene; palladium(2+); dichloride
(1Z,5Z)-cycloocta-1,5-diene;dichloropalladium
PdCl2(cod)
SCHEMBL4248333
Palladium, dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-
MFCD00012412
A804650
Dichloro(1,5-cycloocatadiene)palladium(II)
12193-11-2
doi:10.14272/RRHPTXZOMDSKRS-PHFPKPIQSA-L.1
12107-56-1
10.14272/RRHPTXZOMDSKRS-PHFPKPIQSA-L.1
dichloro[(1,2,5,6-η)-cycloocta-1,5-diene]palladium
Dichloro (1,5-cyclooctadiene) Palladium (II)
1,5-Cyclooctadienepalladium(II) Dichloride
(cis,cis-1,5-Cyclooctadiene)palladium(II) chloride
Cycloocta-1,5-diene; palladium chloride
(5Z)-Cycloocta-1,5-diene;dichloropalladium

MDL Number

MFCD00012412

FAQ

What are the physical and chemical properties of (1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) (CAS: 12107-56-1)?

(1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) is a complex organopalladium compound with a molecular weight of approximately 324.7 g/mol. It has a low melting point and is typically found as a solid or crystalline material. This compound is poorly soluble in water but soluble in common organic solvents such as dichloromethane and tetrahydrofuran. It is highly reactive and exhibits strong coordination properties with palladium, making it useful for catalytic applications. Caution should be exercised due to its reactivity and potential for decomposition upon exposure to air or moisture.

How is (1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) (CAS: 12107-56-1) typically synthesized?

(1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) is synthesized by the complexation of (1Z,5Z)-1,5-cyclooctadiene with dichloropalladium(II) chloride in an inert atmosphere. Commonly, the reaction is carried out in a solvent such as toluene or dichloromethane under nitrogen protection. The synthesis typically involves a stoichiometric ratio of the ligand to the palladium precursor, and the yield is generally around 80-90%.

What industries use (1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) (CAS: 12107-56-1)?

(1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) finds applications in various industries, including pharmaceuticals, where it is used in the synthesis of complex organic molecules. It is also utilized in the production of polymers for advanced materials, sensors for detecting specific chemicals, and semiconductors for electronic devices. This compound is particularly valuable for its catalytic properties in cross-coupling reactions and olefin metathesis.

What precautions should be taken when handling (1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) (CAS: 12107-56-1)?

When handling (1Z,5Z)-1,5-Cyclooctadiene - dichloropalladium (1:1) (CAS: 12107-56-1), it is crucial to use personal protective equipment (PPE) such as gloves, goggles, and a lab coat. This compound is highly reactive and should be stored in a fume hood to minimize exposure to air and moisture. Spills should be immediately addressed with appropriate absorbents, and the area should be well-ventilated. Always consult the Material Safety Data Sheet (MSDS) for detailed safety information and emergency procedures.