Chloro(1,5-cyclooctadiene)rhodium(I) Dimer

Basic Information

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CAS Number

12092-47-6

Molecular Formula

C16H24Cl2Rh2-2

Molecular Weight

493.1 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Hydrocarbons

Basic Physical Properties

Melting Point

216.3-219.2 °C<br />243 °C (dec.)

Boiling Point

153.5°Cat760mmHg

Flash Point

31.7℃

Solubility

Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.

SMILES

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C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]

InChI

InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;;;

InChIKey

PDJQCHVMABBNQW-MIXQCLKLSA-L

LogP

-0.64640

Complexity

72.6

Safety Information

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GHS Hazard Pictograms

H315

H319

H335

Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Stability

hygroscopic

Sensitiveness

Air Sensitive & Hygroscopic

Synonyms & References

English

mu-Chloro(1,5-cyclooctadiene)rhodium(I) dimer
7BR4HR5Q6M
J-400831
chloro (1,5-cyclooctadiene) rhodium (I) dimer
Chloro(1,5-cyclooctadiene)rhodium(I)dimer
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
AKOS015964108
A804617
MFCD00012415
1,5-Cyclooctadiene Rhodium(I) Chloride Dimer
(1Z,5Z)-cycloocta-1,5-diene; rhodium; dichloride
(eta4-1,5-Cyclooctadiene)rhodium chloride dimer
Rhodium-1,5-cyclooctadiene chloride
1,5-Cyclooctadiene, rhodium complex
chloro(1,5-cyclooctadien)rhodium(I) dimer
B1045
bis(1,5-cyclooctadiene)-di-rhodium(i)-dichloride
DI-.MU.-CHLORO-BIS(HAPTO-1,5-CYCLOOCTADIENE)DIRHODIUM
bis(1,5-cyclooctadiene)dirhodium (I) dichloride
EN300-26569719
(1,5-Cyclooctadiene)rhodium chloride dimer
Bis(cycloocta-1,5-diene)dichlorodirhodium;Chloro(1,5-cyclooctadiene)rhodium dimer
(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride
Rhodium 1,5-cyclooctadiene chloride dimer
AMY19657
BIS(CYCLOOCTA-1,5-DIENE)DICHLORODIRHODIUM (I)
Di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]dirhodium
Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di-
Di-mu-chlorobis((1,2,5,6-eta)-1,5-cyclooctadiene)dirhodium
bis(lambda1-rhodium(1+) ion) bis((1Z,5Z)-cycloocta-1,5-diene) dichloride
12092-47-6

MDL Number

MFCD00012415

FAQ

What is Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6)?

Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) is a coordination compound composed of two rhodium atoms each bonded to a chloride ion and a 1,5-cyclooctadiene ligand. It is a pale yellow solid with moderate solubility in organic solvents and is commonly used in catalytic processes due to its unique reactivity and stability properties.

What are the main uses of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6)?

Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) is primarily used as a catalyst in organic synthesis, particularly in hydrogenation and coupling reactions. It finds applications in pharmaceutical research, polymer chemistry, and industrial processes where selective and efficient catalytic activity is required.

Is Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) safe?

Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) is considered hazardous due to its potential toxicity. It should be handled with care, using appropriate personal protective equipment (PPE) such as gloves and goggles. Safety standards recommend avoiding inhalation, ingestion, and skin contact, and ensuring proper ventilation in work areas.

How should Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) be stored?

Chloro(1,5-cyclooctadiene)rhodium(I) Dimer (CAS: 12092-47-6) should be stored in a cool, dry, and dark place in a sealed, airtight container. It is stable under these conditions but should be protected from moisture and air exposure to maintain its chemical integrity and activity.