bis($l^{2}-silanylidene)zirconium | CAS No. 12039-90-6

bis($l^{2}-silanylidene)zirconium

Basic Information

CAS Number

12039-90-6

Molecular Formula

Si2Zr

Molecular Weight

147.4 g/mol

AD

Basic Physical Properties

Melting Point

1790°C

Water Solubility

Insoluble in water. It is insoluble in acids, alkali and aqua regia.

[Si]=[Zr]=[Si]

InChI

InChI=1S/2Si.Zr

InChIKey

GJIKIPCNQLUSQC-UHFFFAOYSA-N

LogP

-0.7641

Topological Polar Surface Area

0.0 Ų

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

18.3

Synonyms & References

English

  • Q8072751
  • Zirconium silicide, 5-10 micron APS
  • EINECS 234-911-1
  • Zirconium silicide, 2-5 micron APS
  • Zirconium disilicide
  • MFCD00151547
  • Zirconium silicide
  • FT-0694102
  • 12039-90-6
  • zirconium disilicide
  • ZIRCONIUM SILICIDE
  • ZIRCONIUM SILICIDE, -325 MESH
  • ZIRCONIUM SILICIDE, POWDER

MDL Number

MFCD00151547

FAQ

What are the physical and chemical properties of bis($l^{2}-silanylidene)zirconium (CAS: 12039-90-6)?

Bis($l^{2}-silanylidene)zirconium is a complex with a molecular weight of approximately 300 g/mol. It is typically crystalline and has low solubility in common organic solvents. Chemically, it exhibits Lewis acidic behavior and displays high reactivity towards nucleophiles, making it useful in organometallic synthesis and catalysis.

How is bis($l^{2}-silanylidene)zirconium (CAS: 12039-90-6) typically synthesized?

Bis($l^{2}-silanylidene)zirconium is prepared by treating zirconium tetrachloride with a silane such as trimethylsilyl chloride in the presence of a suitable base. The reaction is typically carried out at low temperature to improve yield and selectivity, and the product is isolated by filtration and dried under vacuum to remove excess reagents and solvents.

What industries use bis($l^{2}-silanylidene)zirconium (CAS: 12039-90-6)?

Bis($l^{2}-silanylidene)zirconium finds applications in various industries, including pharmaceuticals for metalation reactions, polymers for controlled polymerization processes, and sensors for the detection of specific molecules. It is also used in the synthesis of semiconductors and as a catalyst in organometallic chemistry.

What precautions should be taken when handling bis($l^{2}-silanylidene)zirconium (CAS: 12039-90-6)?

Handle bis($l^{2}-silanylidene)zirconium in a well-ventilated fume hood to prevent inhalation of dust. Wear appropriate personal protective equipment, including gloves and safety goggles. Store the compound in a cool, dry place away from moisture and incompatible substances. In case of a spill, immediately clean up using appropriate absorbents and follow your company's safety data sheet (SDS) guidelines for disposal.

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