Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (1:2:1) | CAS No. 106681-15-6

Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (1:2:1)

Basic Information

CAS Number

106681-15-6

Molecular Formula

C52H46O4P2Ru

Molecular Weight

899.9 g/mol

AD

Basic Physical Properties

Melting Point

>100°C

CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CC(=O)O.CC(=O)O.[Ru]

InChI

InChI=1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;2*1-2(3)4;/h5-32H,1-4H3;2*1H3,(H,3,4);/q;;;+2/p-2

InChIKey

HXHQOYKBZFDKSM-UHFFFAOYSA-L

LogP

10.43760

Complexity

975

Safety Information

View Safety Information

Hazard Statement

H319 Causes serious eye irritation
Serious eye damage/eye irritation
H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

air sensitive

Synonyms & References

English

  • 116128-29-1
  • 106681-15-6
  • (S)-Ru(OAc)2(T-BINAP)
  • E81026
  • Diacetato[(S)-(-)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II)
  • (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane (acetyloxy)ruthenio acetate
  • RU(OAC)2[(R)-TOLBINAP]
  • acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium
  • RU(OAC)2[(S)-TOLBINAP]
  • Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
  • Diacetato[(R)-(+)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II)
  • (R)-Ru(OAc)2(T-BINAP)
  • AKOS015908623
  • Ruthenium, bis(acetato-kO,kO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kP]]-, (OC-6-22)-
  • Ru(OAc)2[(S)-tolbinap]
  • DIACETATO[(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)
  • Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II),  Ru(OAc)2[(S)-tolbinap]
  • Ruthenium, bis(acetato-kO,kO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphe...
  • -binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
  • -bis(di-p-tolylphosphino)-1,1&#039
  • Bis(acetato)[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]]ruthenium
  • DIACETATO[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)
  • C52H46O4P2Ru
  • Ru[(S)-T-BINAP](OCOCH3)2
  • SC10146
  • Diacetato[(S)-(?)-2,2?-bis(di-p-tolylphosphino)-1,1?-binaphthyl]ruthenium(II)
  • DIACETATO[(R)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)
  • Diacetato[(R)-2,2 inverted exclamation marka-bis(di-p-tolylphos

MDL Number

MFCD09753021

FAQ

What are the physical and chemical properties of Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6)?

Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6) is a crystalline solid with a high molecular weight. It is slightly soluble in organic solvents and has limited reactivity under normal conditions. The compound exhibits good stability but can undergo photodegradation in the presence of light. It is often used in catalytic applications and as a precursor in coordination chemistry.

How is Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6) typically synthesized?

Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] is synthesized through a complex organic reaction involving the coordination of ruthenium with acetate and a phosphine ligand. Commonly, this involves a multi-step synthesis using catalytic amounts of a ruthenium precursor, acetate, and 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] ligand, under high purity conditions to ensure high yield and selectivity.

What industries use Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6)?

Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6) is primarily used in the pharmaceutical and semiconductor industries for its catalytic properties. It is also utilized in the development of luminescent materials and as a component in advanced sensor technologies.

What precautions should be taken when handling Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6)?

When handling Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 106681-15-6), it is essential to use appropriate personal protective equipment (PPE) including gloves, goggles, and a lab coat. Always work in a fume hood to minimize exposure. Spills should be handled with caution, using appropriate absorbents, and the area should be ventilated. Refer to the Safety Data Sheet (SDS) for detailed instructions.

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