Rapid, iterative syntheses of unsymmetrical di- and triarylboranes from crystalline aryldifluoroboranes
Literature Information
Publication Date
2023-11-17
DOI
10.1039/D3SC05071H
Impact Factor
9.825
Authors
Douglas Turnbull, Marc-André Légaré
View Original
Abstract
A one-pot procedure to synthesise aryldifluoroboranes, ArBF2, from bench-stable arylsilanes is presented. These ArBF2 react conveniently with aryllithium reagents to form unsymmetrical ArAr′BF and BArAr′Ar′′ in high yield. Examples of all three classes of borane have been characterised crystallographically, allowing for elucidation of geometric and crystal packing trends in crystalline ArBF2.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
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Recommended Compounds
![2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure](https://static.chemtradehub.com/structs/877/877395-58-9-70bf.webp "2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure")
2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol
CAS Number:
877395-58-9
Molecular Formula:
C43H46N2O3
(3-Oxo-1,2,3,4-tetrahydro-2-quinoxalinyl)acetic acid
CAS Number:
136584-14-0
Molecular Formula:
C10H10N2O3
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