Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

Literature Information

Publication Date 2008-08-27
DOI 10.1039/B810426C
Impact Factor 6.222
Authors

Shigehisa Akine, Takashi Matsumoto, Tatsuya Nabeshima


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Abstract

An unprecedented one-handed coiled-coil structure was formed in the crystal of a Zn3La tetranuclear metallohelicate, in which the handedness of both the helical component and the helical array was well controlled by the chiral auxiliary of the flexible acyclic ligand.

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DOI: 10.1039/C8CP91826K

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