![2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure](https://static.chemtradehub.com/structs/127/1279090-25-3-1b84.webp "2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate structure")
2-Methyl-2-propanyl {3-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-3-oxetanyl}carbamate
CAS Number:
1279090-25-3
Molecular Formula:
C20H30BNO5
Mn-electrocatalytic oxidative C(sp3)–H azidation of 2-oxindoles and β-keto esters and azidation–cyclization of tryptamines
Literature Information
Publication Date
2023-11-22
DOI
10.1039/D3QO01716H
Impact Factor
5.281
Authors
Shiwen Fan, Runxia Ma, Aohua Yang, Hongbo Jia, Yufei Dong, Cheng Guo, Jingyun Ren
View Original
Abstract
A concise electrocatalytic oxidative C(sp3)–H azidation approach for constructing 3-azido-oxindoles, α-azido-β-ketol esters and 3a-azido-pyrroloindolines is described, utilizing manganese (Mn) as an azidyl radical transfer reagent. This protocol offers mild, environmentally benign reaction conditions and broad substrate scope. Furthermore, the practicality of this electrocatalytic azidation process could be demonstrated through gram-scale syntheses with good yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2-(7,7-Difluorobicyclo[4.1.0]hept-1-yl)ethanamine structure](https://static.chemtradehub.com/structs/209/2098065-08-6-ff24.webp "2-(7,7-Difluorobicyclo[4.1.0]hept-1-yl)ethanamine structure")
2-(7,7-Difluorobicyclo[4.1.0]hept-1-yl)ethanamine
CAS Number:
2098065-08-6
Molecular Formula:
C9H15F2N
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