![6-Bromo-3-ethyl-3H-imidazo[4,5-b]pyridine structure](https://static.chemtradehub.com/structs/103/1033202-59-3-2a8f.webp "6-Bromo-3-ethyl-3H-imidazo[4,5-b]pyridine structure")
Photoinduced C–H heteroarylation of enamines via quadruple cleavage of CF2Br2
Literature Information
Publication Date
2023-10-20
DOI
10.1039/D3QO01474F
Impact Factor
5.281
Authors
Lingling Zuo, Xiao Geng, Zhifang Li
View Original
Abstract
The C–H functionalization of enamines has attracted much attention over the past few years; however, the heteroarylation of enamines still remains rare. Herein, we wish to report a photoinduced three-component coupling/cyclization reaction for the de novo synthesis of 1,3,4-oxdiazole- or benzothiazole-functionalized enamines via quadruple cleavage of CF2Br2. Notably, the reaction provides an efficient and general approach for the C–H heteroarylation of enamines and exploits a new reactivity of CF2Br2, as the C1 source.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol
CAS Number:
278597-30-1
Molecular Formula:
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CAS Number:
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Molecular Formula:
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