1-isopropyl-3,5-dimethyl-1H-pyrazole-4-carboxylic acid
CAS Number:
1007542-01-9
Molecular Formula:
C9H14N2O2
Difunctionalization of alkenes proceeding with radical 1,2-alkynyl migration in batch and continuous-flow modes
Literature Information
Publication Date
2023-12-02
DOI
10.1039/D3NJ05081E
Impact Factor
3.591
Authors
Ziren Mao, Yiliang Zhou, Jingming Zhang, Chengkou Liu, Chang-Sheng Wang, Xiaobing Yang, Hong Qin, Zheng Fang
View Original
Abstract
An efficient strategy to construct α-alkynyl ketones through electrochemical difunctionalization of alkenes was developed. This method is oxidant-free, metal-free, high-efficiency and eco-friendly, and offers rapid constructions of 1,2-alkynyl migration products through the radical process of 3-exo-dig cyclization. Moreover, the reaction could undergo a successful transformation under continuous-flow conditions.
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Source Journal
New Journal of Chemistry
CiteScore:
5.3
Self-citation Rate:
3.7%
Articles per Year:
2153
NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.
Recommended Compounds
![2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate structure](https://static.chemtradehub.com/structs/833/833452-36-1-7af5.webp "2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate structure")
2-Methyl-2-propanyl [1-(3-nitro-2-pyridinyl)-4-piperidinyl]carbamate
CAS Number:
833452-36-1
Molecular Formula:
C15H22N4O4
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