Ladder-type poly(benzopentalene) derivatives with tunable energy levels by “click” reaction
Literature Information
Publication Date
2012-01-30
DOI
10.1039/C2PY00593J
Impact Factor
5.582
Authors
Dong Wang, Yuzhen Zhao, Hong Gao, Yan Xing, Huai Yang
View Original
Abstract
We have successfully synthesized two types of conjugated polymers, i.e., ladder-type or AB-type poly(benzopentalene) derivative macromoleculars, by Pd-catalyzed self-polycondensation. Incorporating long alkyl chains at the polymer peripheral positions, both polymers have very good solubility and high molecular weight. Thus, the detailed optical and electrochemical properties of the polymers were investigated. At the same time, it was very special that one type of conjugated polymer possessed reactive side groups which can be “clicked” by tetrathiafulvalene (TTF). The energy levels can be obviously changed by the “click” reaction. These results show that ladder-type poly(benzopentalene) derivatives containing reacted side groups are promising candidates for achieving optoelectronic applications.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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CAS Number:
5790-46-5
Molecular Formula:
C13H21NO2
Phenanthro(3,2-b)furan-6(2H)-one, 1,8,9,11b-tetrahydro-7,11-dihydroxy-3,4,9,11b-tetramethyl-, cis-
CAS Number:
99624-92-7
Molecular Formula:
C20H22O4
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